132409-98-4

Basic information

• Product Name: Toluene-4-sulfonic acid (Z)-1-methyl-hept-5-enyl ester
• CAS NO: 132409-98-4
• Molecular Weight: 282.404
• Mol File: 132409-98-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid (Z)-1-methyl-hept-5-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid (Z)-1-methyl-hept-5-enyl ester(132409-98-4)
• EPA Substance Registry System: Toluene-4-sulfonic acid (Z)-1-methyl-hept-5-enyl ester(132409-98-4)

Safety Data

• Hazardous Substances Data: 132409-98-4(Hazardous Substances Data)

Upstream product

• 63281-98-1 (Z)-1-bromohex-4-ene 
• 928-91-6 (Z)-4-hexenol 
• 58822-84-7 (Z)-6-octen-2-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Solvolysis Rates and β-Deuterium Secondary Kinetic Isotope Effects of Some Tertiary and Secondary Alk-5-enyl Derivatives. Evidence for ?-Participation

Tertiary 1,1-dimethylalk-5-enyl chlorides solvolyze in 80percent v/v ethanol with no or moderate rate enhancements attributable to ?-participation.However, secondary β-deuterium kinetic isotope effects (KIE, two deuterated methyl groups) are significantly reduced (kH/kD = 1.22-1.57) relative to the saturated analogues (kH/kD = 1.80), indicating participation of the double bond.Secondary 1-methylalk-5-enyl tosylates show the same trends, i.e., no or very moderate rate enhancements but reduced β-deuterium secondary KIE relative to the saturated analogue.