132682-80-5Relevant articles and documents
Noncryogenic synthesis of functionalized 2-methoxypyridines by halogen-magnesium exchange using lithium dibutyl(isopropyl)magnesate(1-) and lithium chloride
Struk, Lukasz,Sosnicki, Jacek G.
experimental part, p. 735 - 746 (2012/04/04)
2-Methoxypyridines functionalized in the 3-, 5-, or 6-position and 2,6-dimethoxypyridines functionalized in the 3-position were prepared from the corresponding bromo or iodo analogues by using lithium dibutyl(isopropyl) magnesate(1-) and lithium chloride
Electrosynthesis of triorganylphosphines from organic halides and chlorophosphines, catalyzed by nickel complexes
Budnikova,Kargin,Sinyashin
, p. 524 - 528 (2007/10/03)
The possibility of cross coupling of organic halides and chlorophosphines under the action of electrochemically generated Ni(0) complexes of 2,2′-bipy is shown. The final triorganylphosphines are formed by several pathways, including reaction of the σ complex of ArNiX with chlorophosphine and electron transfer-induced reductive elimination of Ph2PArNiX, leading to the cross-coupling product.
Carbonylation catalyst system
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, (2008/06/13)
A catalyst system, which comprises: a) a source of a Group VIII metal; b) a phosphine having an aromatic substituent which contains an imino nitrogen atom; c) a source of protons; and d) a tertiary amine.