1327155-92-9

Basic information

• Product Name: [Ag(triphenylphosphine)2(formato)]*(dichloromethane)
• CAS NO: 1327155-92-9
• Molecular Weight: 762.401
• Mol File: 1327155-92-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ag(triphenylphosphine)2(formato)]*(dichloromethane)(CAS DataBase Reference)
• NIST Chemistry Reference: [Ag(triphenylphosphine)2(formato)]*(dichloromethane)(1327155-92-9)
• EPA Substance Registry System: [Ag(triphenylphosphine)2(formato)]*(dichloromethane)(1327155-92-9)

Safety Data

• Hazardous Substances Data: 1327155-92-9(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 13126-70-0 silver(I) formate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Polynuclear silver(I) complexes of triphenylphosphine and 2-aminopyrimidine: Synthesis, structural characterization and spectroscopic properties

The reactions of triphenylphosphine (PPh3) and 2-aminopyrimidine (AMP) ligand with Ag salts in the mixed solvent of methanol (MeOH) and dichloromethane (CH2Cl2) lead to the mono-, di-, and tetranuclear complexes, [Ag(PPh3)(AMP)2](BF4) (1), [Ag2(PPh3)4(AMP)2(SO 4)] (2), [Ag4 (PPh3)4(AMP) 2(NO3)4]∞ (3) and [Ag 4(PPh3)4(AMP)2(Ac)4] ∞ (Ac = CH3COO) (4) and [Ag(PPh3) 2(HCOO)]·CH2Cl2 (5). Complexes 1 and 2 are of 1D infinite chain structure controlled by intermolecular hydrogen bonds of type R22(8). In complexes 3 and 4, the 1D infinite chains are formed through the bridging-chelating anions (nitrate for 3 and acetate for 4) and the N,N′-bridging ligand AMP. Five-coordinated modes of Ag(I) are observed in 3 and 4. In the synthesis reaction of complex 5, AMP only acts as catalyst rather than ligand. All the complexes are characterized by X-ray diffraction. Compounds 1-4 are also characterized by fluorescence and 1H, 31P NMR spectroscopy.