1330681-32-7

Basic information

• Product Name: 4-isobutylphenyl(mesityl)iodonium trifluoromethanesulfonate
• Synonyms: 4-isobutylphenyl(mesityl)iodonium trifluoromethanesulfonate
• CAS NO: 1330681-32-7
• Molecular Weight: 528.374
• Mol File: 1330681-32-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-isobutylphenyl(mesityl)iodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-isobutylphenyl(mesityl)iodonium trifluoromethanesulfonate(1330681-32-7)
• EPA Substance Registry System: 4-isobutylphenyl(mesityl)iodonium trifluoromethanesulfonate(1330681-32-7)

Safety Data

• Hazardous Substances Data: 1330681-32-7(Hazardous Substances Data)

Upstream product

• 2926-30-9 sodium triflate 
• 153624-38-5 4-isobutyl-phenylboronic acid 
• 33035-41-5 2-(diacetoxyiodo)mesitylene 
• 1493-13-6 trifluorormethanesulfonic acid 
• 538-93-2 1-phenyl-2-methylpropane 

Downstream Products

• 51146-56-6 (S)-ibuprofen 
• 81576-55-8 (S)-(+)-methyl 2-(4-isobutylphenyl)propionate 
• 92978-26-2 5-(4-isobutylphenyl)-2,2,5-trimethyl-1,3-dioxane-4,6-dione 
• 666214-15-9 4-methoxyphenyl 2-(4-isobutylphenyl)propanoate 
• 1613334-10-3 1-(p-isobutylphenyl)-2-(p-methoxyphenyl)-3,3-dimethylcyclopentene 

Relevant articles and documents

Refining boron-iodane exchange to access versatile arylation reagents

Aryl(Mes)iodonium salts, which are multifaceted aryl transfer reagents, are synthesized via boron-iodane exchange. Modification to both the nucleophilic (aryl boron) and electrophilic (mesityl-λ3-iodane) reaction components results in improved yield and faster reaction time compared to previous conditions. Mechanistic studies reveal a pathway that is more like transmetallation than SEAr.