1332358-75-4

Basic information

• Product Name: ethyl 2-(pyrimidin-2-yl)benzoate
• Synonyms: ethyl 2-(pyrimidin-2-yl)benzoate
• CAS NO: 1332358-75-4
• Molecular Weight: 228.25
• Mol File: 1332358-75-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl 2-(pyrimidin-2-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-(pyrimidin-2-yl)benzoate(1332358-75-4)
• EPA Substance Registry System: ethyl 2-(pyrimidin-2-yl)benzoate(1332358-75-4)

Safety Data

• Hazardous Substances Data: 1332358-75-4(Hazardous Substances Data)

Upstream product

• 380430-53-5 2-(ethoxycarbonyl)phenylboronic acid 
• 1722-12-9 2-chloropyrimidine 
• 4595-60-2 2-bromopyrimidine 
• 269409-99-6 ethyl 2-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)benzoate 
• 1603-79-8 phenylglyoxylic acid ethyl ester 
• 7431-45-0 2-phenylpyrimidine 
• 104388-04-7 N-t-butyl-3,3-bisethoxycarbonyl oxaziridine 

Downstream Products

• 7431-45-0 2-phenylpyrimidine 

Relevant articles and documents

Nickel-catalyzed reductive defunctionalization of esters in the absence of an external reductant: Activation of C-O bonds

The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C-O bond in O-Alkyl esters is reported. Various groups, such as N-containing heterocycles, esters, amides, and even arene rings can function as a directing group.

Palladium-catalyzed direct alkoxycarbonylation of aromatic C-H bonds via selective C-C cleavage of a-keto esters

A novel palladium-catalyzed direct alkoxycarbonylation of 2-arylpyridines, 2-arylquinolines, benzo[h]quinolines, 2-phenylpyrimidines, N-pyrimidine pyrroles and N-pyrimidine indoles via aromatic C-H bond activation and selective C-C cleavage of a-keto esters has been developed. The method has the advantages of wide functional group tolerance, high selectivity, broad range of substrates and good yields.