1334429-81-0Relevant articles and documents
Cyclization of Alkyne-Azide with Isonitrile/CO via Self-Relay Rhodium Catalysis
Zhang, Zhen,Xiao, Fan,Huang, Baoliang,Hu, Jincheng,Fu, Bin,Zhang, Zhenhua
, p. 908 - 911 (2016/03/15)
A self-relay rhodium(I)-catalyzed cyclization of alkyne-azides with two σ-donor/π-acceptor ligands (isonitriles and CO) to form sequentially multiple-fused heterocycle systems via tandem nitrene transformation and aza-Pauson-Khand cyclization has been dev
Umpolung reactivity of indole through gold catalysis
Lu, Biao,Luo, Yingdong,Liu, Lianzhu,Ye, Longwu,Wang, Yanzhao,Zhang, Liming
supporting information; experimental part, p. 8358 - 8362 (2011/10/31)
Electrophilic indole? Indoles, which are typically nucleophilic, can be made electrophilic through gold catalysis. By using an ortho-azido group to deliver a nitrene intramolecularly, an arylalkyne is converted into a gold carbene intermediate containing an indole skeleton that is highly electrophilic at the 3-position. A range of functionalized indoles is readily accessed by utilizing this strategy.