13399-33-2

Basic information

• Product Name: Benzene, 1-(1,2-dimethyl-1-propenyl)-4-methoxy-
• CAS NO: 13399-33-2
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 13399-33-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,2-dimethyl-1-propenyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,2-dimethyl-1-propenyl)-4-methoxy-(13399-33-2)
• EPA Substance Registry System: Benzene, 1-(1,2-dimethyl-1-propenyl)-4-methoxy-(13399-33-2)

Safety Data

• Hazardous Substances Data: 13399-33-2(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 3017-70-7 2-bromo-3-methylbut-2-ene 
• 24470-78-8 isopropyltriphenylphosphonium iodide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 67344-14-3 (3-methylbut-2-en-2-yl)lithium 
• 623-12-1 4-chloromethoxybenzene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 513-35-9 2-methyl-but-2-ene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 115-22-0 3-Hydroxy-3-methyl-2-butanone 
• 408319-04-0 3-Hydroxy-2.2-dimethyl-3--buttersaeureethylester 
• 27925-42-4 3-Hydroxy-3-(4-methoxy-phenyl)-2,2-dimethyl-butyric acid 
• 83208-00-8 C₁₂H₁₆O*C₁₂H₁₄N₂⁽²⁺⁾ 
• 108773-46-2 4-(4-Methoxy-phenyl)-3,3,4-trimethyl-oxetan-2-one 

Downstream Products

• 83208-00-8 C₁₂H₁₆O*C₁₂H₁₄N₂⁽²⁺⁾ 
• 141298-98-8 1-(2-Chloro-2-methyl-1-methylene-propyl)-4-methoxy-benzene 
• 141298-97-7 1-(1,2-Dichloro-1,2-dimethyl-propyl)-4-methoxy-benzene 
• 108201-75-8 1,1,4,-trimethyl-4-isopropyl-7-methoxy-2-p-anisyl-1,2,3,4-tetrahydronaphthalene 
• 28443-29-0 2-<4-Hydroxy-3.5-dinitro-phenyl>-3-methyl-butan 
• 91967-90-7 (+/-)-4-Hydroxy-1-(1.2-dimethyl-propyl)-benzol 
• 69164-46-1 3-Hydroperoxy-2-(4-methoxyphenyl)-3-methyl-1-buten 
• 67-64-1 acetone 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 
• 28114-95-6 3-methyl-2-(4-methoxyphenyl)butan-2-ol 
• 106167-99-1 2-(4-methoxy-phenyl)-3-methyl-butane-2,3-diol 

Relevant articles and documents

Contra-Thermodynamic Positional Isomerization of Olefins

A light-driven method for the contra-thermodynamic positional isomerization of olefins is described. In this work, stepwise PCET activation of a more substituted and more thermodynamically stable olefin substrate is mediated by an excited-state oxidant an

Extending the Substrate Scope in the Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with Ir-P Stereogenic Aminophosphine-Oxazoline Catalysts

Air-stable and readily available Ir-catalyst precursors modified with MaxPHOX-type ligands have been successfully applied in the challenging asymmetric hydrogenation of tetrasubstituted olefins under mild reaction conditions. Gratifyingly, these catalyst precursors are able to efficiently hydrogenate not only a range of indene derivatives (ee's up to 96%) but also 1,2-dihydronapthalene derivatives and acyclic olefins (ee's up to 99%), which both constitute the most challenging substrates for this transformation.

Direct catalytic cross-coupling of alkenyllithium compounds

A catalytic method for the direct cross-coupling of alkenyllithium reagents with aryl and alkenyl halides is described. The use of a catalyst comprising Pd2(dba)3/XPhos allows for the stereoselective preparation of a wide variety of substituted alkenes in high yields under mild conditions. In addition (1-ethoxyvinyl)lithium can be efficiently converted into substituted vinyl ethers which, after hydrolysis, give readily access to the corresponding methyl ketones in a one pot procedure.