13435-09-1

Basic information

• Product Name: dianilinodimethylsilane
• Synonyms: dianilinodimethylsilane;1,1-dimethyl-n,n'-diphenyl-silanediamin;1,1-dimethyl-N,N'-diphenyl-Silanediamine;Silanediamine,1,1-dimethyl-N,N'-diphenyl-;N,N'-Diphenyldimethylsilanediamine;α,α-Dimethyl-N,N'-diphenylsilanediamine;Einecs 236-564-1
• CAS NO: 13435-09-1
• Molecular Formula: C₁₄H₁₈N₂Si
• Molecular Weight: 242.39162
• EINECS: 236-564-1
• Mol File: 13435-09-1.mol
• Article Data: 5

Chemical Properties

• Melting Point: 56 °C(Solv: ligroine (8032-32-4))
• Boiling Point: 302.5°C at 760 mmHg
• Flash Point: 136.8°C
• Appearance: /
• Density: 1.077g/cm³
• Vapor Pressure: 0.000983mmHg at 25°C
• Refractive Index: 1.613
• PKA: 5.27±0.38(Predicted)
• CAS DataBase Reference: dianilinodimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: dianilinodimethylsilane(13435-09-1)
• EPA Substance Registry System: dianilinodimethylsilane(13435-09-1)

Safety Data

• Hazardous Substances Data: 13435-09-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H18N2Si/c1-17(2,15-13-9-5-3-6-10-13)16-14-11-7-4-8-12-14/h3-12,15-16H,1-2H3

Upstream product

• 75-78-5 dimethylsilicon dichloride 
• 62-53-3 aniline 
• 3574-04-7 hexamethylcyclotrisilathiane 
• 6143-68-6 bis(diethylamino)dimethylsilane 
• 1020-84-4 2,2,4,4,6,6,8,8-octamethyl-cyclotetrasilazane 

Downstream Products

• 17995-11-8 N,N'-Diphenyl-trimethyl-chlor-cyclodisilazan 
• 17932-58-0 Acetoxy-anilino-dimethyl-silan 
• 3284-06-8 N,N'-diphenyltetramethylcyclodisilazane 
• 18407-25-5 N,N'-Diphenyl-dimethyl-dichlor-cyclodisilazan 
• 81720-62-9 3,5-diphenylcyclo-1-oxa-3,5-diaza-2,4,6-trimethyl-2,4,6-triborane 
• 1360059-02-4 Li(O(C₂H₅)2)3⁽¹⁺⁾*Al((CH₃)2Si(NC₆H₅)2)2^(1-)*C₆H₅CH₃=[Li(O(C₂H₅)2)3][Al((CH₃)2Si(NC₆H₅)2)2]*C₆H₅CH₃ 
• 1360059-03-5 Li(O(C₂H₅)2)3⁽¹⁺⁾*Ga((CH₃)2Si(NC₆H₅)2)2^(1-)*C₆H₅CH₃=[Li(O(C₂H₅)2)3][Ga((CH₃)2Si(NC₆H₅)2)2]*C₆H₅CH₃ 

Relevant articles and documents

Insertion of phenyl isocyanate into monoand diaminosilanes

The aminosilanes MenSi(NRR')4-n (n = 2,3) with NRR' = ethylamino (NHEt), n-propylamino (NHnPr), sec-butylamino (NHsBu), n-octylamino (NHnOct), n-dodecylamino (NHnDodec), allylamino (NHAll), tert-butylamino (NHtBu), diethylamino (NEt2), and anilino (NHPh) were synthesized and their reactions with phenyl isocyanate were studied. In all cases of these silanes Me3SiNRR' and Me2Si(NRR')2 formal insertion of the -NCO group into their Si-N bonds was observed, i.e. formation of products with Si-N (rather than Si-O) bonds was found. In some cases, the products could be crystallized and their molecular structures have been elucidated with single-crystal X-ray diffraction analyses.

Synthesis and application of some dianilinosilanes, bis (trimethylsilyl) phenylenediamines and dialkyl benzo-1,3,2-diazasilolines as antioxidants

A number of dialkyl or diphenyl dianilinosilanes, bis (trimethylsilyl) phenylenediamines and dialkyl benzo-1,3,2-diazasilolines were synthesized and used as antioxidants for lubricating base oils. Thermal analysis methods (DSC, TG and DTG) and IR techniqu