13487-64-4Relevant articles and documents
Low temperature hydrodeoxygenation of phenols under ambient hydrogen pressure to form cyclohexanes catalysed by Pt nanoparticles supported on H-ZSM-5
Ohta, Hidetoshi,Yamamoto, Kentaro,Hayashi, Minoru,Hamasaka, Go,Uozumi, Yasuhiro,Watanabe, Yutaka
, p. 17000 - 17003 (2015)
The hydrodeoxygenation of various phenols to form cyclohexanes was achieved at 110 °C under an H2 atmosphere at ambient pressure using a Pt/H-ZSM-5 catalyst and octane as the solvent.
Examples of xylochemistry: Colorants and polymers
Kühlborn, Jonas,Danner, Ann-Kathrin,Frey, Holger,Iyer, Rishab,Arduengo, Anthony J.,Opatz, Till
supporting information, p. 3780 - 3786 (2017/08/23)
Against the backdrop of modern sustainable chemistry and valorization of biomass for chemical raw materials, the syntheses of indigo dyes and polyamides as representatives of two classes of everyday chemical products based on xylochemicals are described. Wood-derived starting materials were transformed into functional materials using the principles of green chemistry to expand the scope of products gained from renewable resources. The indigo dyes were synthesized in a short, straightforward sequence starting from vanillin. Two polyamides, representatives of an important class of polymers, were obtained from 4-propylcyclohexanol, which is one of the longest known (and most abundant) hydrogenative depolymerization products of lignin.
Hydrodeoxygenation of phenols as lignin models under acid-free conditions with carbon-supported platinum catalysts
Ohta, Hidetoshi,Kobayashi, Hirokazu,Hara, Kenji,Fukuoka, Atsushi
supporting information; experimental part, p. 12209 - 12211 (2011/12/21)
Carbon-supported Pt catalysts are highly active and reusable for the aqueous-phase hydrodeoxygenation of phenols as lignin models without adding any acids. It is suggested that Pt/carbon facilitates the hydrogenation of phenols and the hydrogenolysis of the resulting cyclohexanols. The Royal Society of Chemistry 2011.