1350747-57-7

Basic information

• Product Name: [1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride][FeCl(N(SiMe₃)2)2]
• CAS NO: 1350747-57-7
• Molecular Weight: 806.839
• Mol File: 1350747-57-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride][FeCl(N(SiMe₃)2)2](CAS DataBase Reference)
• NIST Chemistry Reference: [1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride][FeCl(N(SiMe₃)2)2](1350747-57-7)
• EPA Substance Registry System: [1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride][FeCl(N(SiMe₃)2)2](1350747-57-7)

Safety Data

• Hazardous Substances Data: 1350747-57-7(Hazardous Substances Data)

Upstream product

• 18544-54-2 cobalt(II) bis(trimethylsilyl)amide 
• 258278-25-0 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride 

Relevant articles and documents

Aminolysis of bis[bis(trimethylsilyl)amido]iron and -cobalt as a versatile route to N-heterocyclic carbene complexes

A range of new N-heterocyclic carbene complexes of iron(II) and cobalt(II) have been conveniently obtained by the aminolysis of bis[bis(trimethylsilyl) amido]iron and -cobalt precursors with imidazol(in)ium salts. Whereas sterically less hindered salts produced the tetrahedral complexes [M(carbene) 2Cl2] (M = Fe), bulkier salts gave the three-coordinate [M(carbene){N(SiMe3)2}Cl] (M = Fe, Co), which serve as versatile precursors to a range of derivatives; mechanistic aspects of the reaction are discussed.