1354974-33-6

Basic information

• Product Name: C₃₈H₅₅Br₂FO₃
• Synonyms: C₃₈H₅₅Br₂FO₃
• CAS NO: 1354974-33-6
• Molecular Weight: 738.659
• Mol File: 1354974-33-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₈H₅₅Br₂FO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₅₅Br₂FO₃(1354974-33-6)
• EPA Substance Registry System: C₃₈H₅₅Br₂FO₃(1354974-33-6)

Safety Data

• Hazardous Substances Data: 1354974-33-6(Hazardous Substances Data)

Upstream product

• 7144-08-3 Cholesteryl chloroformate 
• 171503-39-2 1,1-dibromo-1-fluoro-4-phenyl-2-butanol 

Downstream Products

• 1354974-47-2 C₃₈H₅₅FO₃ 

Relevant articles and documents

Preparation of (Z)-1-fluoro-1-alkenyl carboxylates, carbonates and carbamates through chromium mediated transformation of dibromofluoromethylcarbinyl esters and the reactivity as double acyl group donors

CrCl2/Mn-mediated transformation of various dibromofluoromethylcarbinyl esters including carboxylates, carbonates and carbamates provided 1-fluoro-1-alkenyl esters via [2,3]-sigmatropic rearrangement of ester group. Reaction proceeded by using CrCl2/Mn system under mild conditions (in THF at room temperature) to give 1-fluoro-1-alkenyl esters in good yield with an excellent Z selective manner. 1-Fluoro-1-alkenyl ester thus obtained acts as a double acyl donor in the reaction with necleophiles such as amine, thiol, alcohol as well as bifunctional necleophiles such as ethylene diamine derivative.