135507-99-2

Basic information

• Product Name: 2,2-bis(4-fluorophenyl)-2-hydroxyethyl acetate
• Synonyms: 2,2-bis(4-fluorophenyl)-2-hydroxyethyl acetate
• CAS NO: 135507-99-2
• Molecular Weight: 292.282
• Mol File: 135507-99-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,2-bis(4-fluorophenyl)-2-hydroxyethyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-bis(4-fluorophenyl)-2-hydroxyethyl acetate(135507-99-2)
• EPA Substance Registry System: 2,2-bis(4-fluorophenyl)-2-hydroxyethyl acetate(135507-99-2)

Safety Data

• Hazardous Substances Data: 135507-99-2(Hazardous Substances Data)

Upstream product

• 6175-14-0 1,1-bis-(4-fluorophenyl)ethene 
• 33840-74-3 1-(phenylsulfinyl)propan-2-one 
• 14284-89-0 manganese(III) acetylacetonate 
• 64-19-7 acetic acid 

Relevant articles and documents

Manganese(III)-Mediated Free-Radical Cyclization of Active Methylene Compounds, Alkenes and Molecular Oxygen. Syntheses of Sulfur- and Phosphorus-Containing 1,2-Dioxan-3-ols

The reactions of β-keto sulfoxide, β-keto sulfones, or β-keto phosphinate with 1,1-disubstituted ethenes in the presence of manganese(III) acetate and molecular oxygen yielded 4-phenylsulfinyl-, 4-phenylsulfonyl-, or 4-phosphinoyl-1,2-dioxan-3-ols 3 in moderate-to-good yields. m-Chloroperbenzoic acid oxidation of 4-phenylsulfinyl-1,2-dioxan-3-ols gave the corresponding 4-phenylsulfonyl derivatives.The temperature dependence of the reactions was observed and the stereochemistry of the 1,2-dioxan-3-ols are discused.