135638-41-4

Basic information

• Product Name: (R)-3-benzyloxycarbonyl-5-<(Z)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)vinyl>-2,2-dimethyl-1,3-oxazolidine
• Synonyms: (R)-3-benzyloxycarbonyl-5-<(Z)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)vinyl>-2,2-dimethyl-1,3-oxazolidine
• CAS NO: 135638-41-4
• Molecular Weight: 434.489
• Mol File: 135638-41-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-3-benzyloxycarbonyl-5-<(Z)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)vinyl>-2,2-dimethyl-1,3-oxazolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-benzyloxycarbonyl-5-<(Z)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)vinyl>-2,2-dimethyl-1,3-oxazolidine(135638-41-4)
• EPA Substance Registry System: (R)-3-benzyloxycarbonyl-5-<(Z)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)vinyl>-2,2-dimethyl-1,3-oxazolidine(135638-41-4)

Safety Data

• Hazardous Substances Data: 135638-41-4(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 135582-86-4 (S)-3-benzyloxycarbonyl-2,2-dimethyl-5-o-nitrobenzoyloxymethyl-1,3-oxazolidine 
• 134038-72-5 (S)-3-benzyloxycarbonylamino-2-hydroxy-1-(o-nitrobenzoyloxy)propane 
• 134038-71-4 (S)-4-benzyloxycarbonylaminomethyl-2,2-dimethyl-1,3-dioxolane 
• 134038-73-6 benzyl (S)-5-hydroxymethyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate 
• 135582-93-3 (S)-3-[N-(benzyloxycarbonyl)amino]-1,2-propanediol 
• 134038-74-7 benzyl (S)-5-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate 
• 121056-95-9 trimethyl 2-(tert-butoxycarbonylamino)phosphonoacetate 
• 135582-88-6 (S)-3-benzyloxycarbonyl-5-methoxycarbonyl-2,2-dimethyl-1,3-oxazolidine 
• 135582-87-5 (S)-methyl 3-(benzyloxycarbonylamino)-2-hydroxypropanoate 
• 42491-79-2 (2S)-3-{[(benzyloxy)carbonyl]amino}-2-hydroxypropanoic acid 

Downstream Products

• 33404-78-3 negamycin 
• 142683-63-4 (R)-3-benzyloxycarbonyl-5-<(S)-2-(tert-butoxycarbonylamino)-2-carboxyethyl>-2,2-dimethyl-1,3-oxazolidine 
• 142683-65-6 (R)-3-benzyloxycarbonyl-5-<(R)-2-(tert-butoxycarbonylamino)-3-carboxypropyl>-2,2-dimethyl-1,3-oxazolidine 
• 142683-64-5 (R)-3-benzyloxycarbonyl-5-<(R)-2-(tert-butoxycarbonylamino)-3-(methoxycarbonyl)propyl>-2,2-dimethyl-1,3-oxazolidine 
• 142683-70-3 benzyl <(3R,5R)-6-benzyloxycarbonylamino-3-tert-butoxycarbonylamino-5-hydroxyhexanoyl-1-methylhydrazino>-acetate 
• 142683-69-0 (R)-3-benzyloxycarbonyl-5-<(R)-4-(2-benzyloxycarbonyl-2-methylhydrazino)-2-tert-butoxycarbonyl-4-oxobutyl>-2,2-dimethyl-1,3-oxazolidine 
• 134038-76-9 (R)-3-benzyloxycarbonyl-5-<(S)-N-tert-butoxycarbonylalanin-3-yl>-2,2-dimethyl-1,3-oxazolidine 
• 145240-76-2 2(S)-benzyloxycarbonylamino-3-{4,4'-bisbenzyloxy-3'-[2(S)-benzyloxycarbonyl-2-(5-benzyloxycarbonylamino-2(S)-tert-butoxycarbonylamino-4(R)-hydroxypentanoylamino)ethyl]biphenyl-3-yl}propionic acid 
• 134038-87-2 benzyl 5,17-bisbenzyloxy-14(S)-benzyloxycarbonylamino-11(S)-(3-benzyloxycarbonylamino-2(R)-hydroxypropyl)-10,13-dioxo-9,12-diazatricyclo[14.3.1.12,6]-henicosa-1(19),2,4,6(21),16(20),17-hexaene-8(S)-carboxylate 
• 100217-74-1 biphenomycin B 
• 134038-76-9 (R)-3-Benzyloxycarbonyl-5-<(S)-N-tert-butoxycarbonylalanin-3-yl>-2,2-dimethyl-1,3-oxazolidine 
• 134038-86-1 benzyl 2(S)-(5-benzyloxycarbonylamino-2(S)-tert-butoxycarbonylamino-4(R)-hydroxypentanoylamino)-3-[4,4'-bisbenzyloxy-3'-(2(S)-benzyloxycarbonylamino-2-pentafluorophenyloxycarbonylethyl)biphenyl-3-yl]propionate 
• 135582-94-4 (R)-3-benzyloxycarbonyl-5-<(S)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)ethyl>-2,2-dimethyl-1,3-oxazolidine 
• 135582-94-4 (R)-3-benzyloxycarbonyl-5-<(S)-2-(tert-butoxycarbonylamino)-2-(methoxycarbonyl)ethyl>-2,2-dimethyl-1,3-oxazolidine 

Relevant articles and documents

Total synthesis of the biphenomycins; II. Synthesis of protected (2S,4R)-4-hydroxyornithines

Improved synthetic methods for the preparation of three differently protected (2S,4R)-4-hydroxyornithine (10, 16, 24) have been developed which obviously can be used for the construction of the other stereoisomers. Formation of the corresponding α,β-dideh