135710-38-2Relevant articles and documents
Green synthesis of (R)-terbutaline for recyclable catalytic asymmetric transfer hydrogenation in ionic liquids
Uchimoto, Hitomi,Ikeda, Miki,Tanida, Saori,Ohhashi, Kayo,Chihar, Yoshiko,Shigeta, Takashi,Arimitsu, Kenji,Yamashit, Masayuki,Nishide, Kiyoharu,Kawasaki, Ikuo
, p. 389 - 395 (2017/04/14)
We synthesize optically active (R)-terbutaline 2, which is an anti-asthmatic drug, through recyclable catalytic asymmetric transfer hydrogenation (RCATH). Various chloroketones 4 were prepared and RCATH was performed on them. The products exhibit moderate
Thermally activated, single component epoxy systems
Unruh, David A.,Pastine, Stefan J.,Moreton, Jessica C.,Frechet, Jean M. J.
experimental part, p. 6318 - 6325 (2012/06/18)
A single component epoxy system in which the resin and hardener components found in many two-component epoxies are combined onto the same molecule is described. The single molecule precursor to the epoxy resin contains both multiple epoxide moieties and a
Synthesis of supercritical carbon dioxide soluble perfluorinated dendrons for surface modification
Luscombe, Christine K.,Proemmel, Steffen,Huck, Wilhelm T. S.,Holmes, Andrew B.,Fukushima, Hitoshi
, p. 5505 - 5513 (2008/02/09)
(Chemical Equation Presented) The rational design, synthesis, and characterization of a series of novel perfluorinated dendrons 14a,b, 25a,b, 26a,b, and 18 are described. The dendrimers were designed to have a thiol at the focal point for attachment to a gold surface to enable the fabrication of self-assembled monolayers (SAMs). Perfluorinated tails were attached to the periphery to provide solubility in supercritical carbon dioxide, and to increase the hydrophobicity and the stability of self-assembled monolayers formed. Mitsunobu reactions were utilized to provide high-yielding steps allowing large-scale production of the novel dendrimers.