1360895-89-1Relevant articles and documents
Synthesis of multi-substituted vinylsilanes via copper(i)-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates
Xu, Yun-He,Wu, Liu-Hai,Wang, Jun,Loh, Teck-Peng
supporting information, p. 7195 - 7197 (2014/07/07)
An efficient and general copper(i)-catalyzed method for the synthesis of multi-substituted vinylsilanes is reported. Multi-substituted allenes with electron-withdrawing groups and propiolate derivatives reacted well with (dimethylphenylsilyl)boronic acid
Activation of Si-Si bonds for copper(I)-catalyzed conjugate silylation
Iannazzo, Laura,Molander, Gary A.
, p. 4923 - 4926,4 (2020/08/24)
Several alkyl- and vinylsilanes were prepared through the copper(I)-catalyzed conjugate silylation of α,β-unsaturated compounds. Optimal reaction conditions were first investigated to realize the conjugate addition of a nucleophilic silicon species to poo