136412-37-8Relevant articles and documents
ENANTIOSELECTIVE CONJUGATE ADDITION TO CYCLIC ENONES WITH (S)-MAPP-CUPRATES
Rossiter, Bryant E.,Eguchi, Masakatsu,Hernandez, Amelia E.,Vickers, Denise,Medich, John,et al.
, p. 3973 - 3976 (1991)
Chiral amidocuprates, formed from CuI, n-butyl or methyl lithium and (S)-N-methyl-1-phenyl-2-(1-piperidinyl)ethanamine, (S)-MAPP, react enantioselectively with 5, 6, 7 and 8-membered cyclic enones to give products with up to 97percent e.e.The synthesis of (S)-MAPP is also reported.