1365271-95-9

Basic information

• Product Name: 5-Fluoro-1-MethylbenziMidazole
• Synonyms: 5-Fluoro-1-MethylbenziMidazole
• CAS NO: 1365271-95-9
• Molecular Formula: C8H7FN2
• Molecular Weight: 150.1529832
• Mol File: 1365271-95-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-Fluoro-1-MethylbenziMidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Fluoro-1-MethylbenziMidazole(1365271-95-9)
• EPA Substance Registry System: 5-Fluoro-1-MethylbenziMidazole(1365271-95-9)

Safety Data

• Hazardous Substances Data: 1365271-95-9(Hazardous Substances Data)

Upstream product

• 64-18-6 formic acid 
• 704-05-2 (4-fluoro-2-nitrophenyl)-(methyl)amine 
• 364-74-9 1,4-difluoro-2-nitrobenzene 
• 124-38-9 carbon dioxide 
• 367-31-7 4-fluoro-1,2-phenylenediamine 
• 122-51-0 orthoformic acid triethyl ester 
• 401567-10-0 4-fluoro-N₁-methylbenzene-1,2-diamine 

Downstream Products

• 1541022-45-0 C₁₄H₁₁FN₂ 
• 1612157-19-3 C₁₅H₁₃FN₂ 
• 1612157-21-7 C₁₅H₁₃FN₂O 
• 1539720-74-5 C₁₄H₁₀F₂N₂ 
• 1612157-22-8 C₁₆H₁₃FN₂ 

Relevant articles and documents

Cu-Catalyzed C-H Allylation of Benzimidazoles with Allenes

CuH-catalyzed intramolecular cyclization and intermolecular allylation of benzimidazoles with allenes have been described. The reaction proceeded smoothly with the catalytic system of Cu(OAc)2/Xantphos and catalytic amount of (MeO)2MeSiH. This protocol features mild reaction conditions and a good tolerance of substrates bearing electron-withdrawing, electron-donating, or electron-neutral groups. A new catalytic mechanism was proposed for this copper hydride catalytic system.

Photoreactivity of monofluorinated 2-azidobenzimidazoles towards carboxylic acids

Aiming at the development of new photolabeling agents, the synthesis and photoreactivity of all monofluorinated derivatives of 2-azido-1-methylbenzimidazole are described. In the case of 4-, 5-, or 7-fluorination, irradiation in the presence of carboxylic