136656-75-2

Basic information

• Product Name: (R)-(-)-1-(benzenesulfanyl)-2-butanol
• Synonyms: (R)-(-)-1-(benzenesulfanyl)-2-butanol
• CAS NO: 136656-75-2
• Molecular Weight: 182.287
• Mol File: 136656-75-2.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: (R)-(-)-1-(benzenesulfanyl)-2-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-1-(benzenesulfanyl)-2-butanol(136656-75-2)
• EPA Substance Registry System: (R)-(-)-1-(benzenesulfanyl)-2-butanol(136656-75-2)

Safety Data

• Hazardous Substances Data: 136656-75-2(Hazardous Substances Data)

Upstream product

• 7205-91-6 phenylthiomethyl chloride 
• 6819-41-6 sodium n-propoxide 
• 100-68-5 methyl-phenyl-thioether 
• 123-38-6 propionaldehyde 
• 57814-09-2 1-(phenylthio)-2-butanone 
• 139193-51-4 (±)-1-(phenylthio)butan-2-yl acetate 
• 106-88-7 ethyloxirane 
• 930-69-8 sodium thiophenolate 
• 96-09-3 styrene oxide 
• 872313-01-4 C₆H₁₄OS 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 201230-82-2 carbon monoxide 

Downstream Products

• 67210-25-7 ((R)-1-Naphthalen-1-yl-ethyl)-carbamic acid (R)-1-phenylsulfanylmethyl-propyl ester 
• 67210-31-5 ((R)-1-Naphthalen-1-yl-ethyl)-carbamic acid (S)-1-phenylsulfanylmethyl-propyl ester 
• 106-88-7 (R)-(+)-1,2-epoxybutane 
• 139193-51-4 (±)-1-(phenylthio)butan-2-yl acetate 
• 1316861-30-9 C₁₃H₁₈O₂S 
• 139193-30-9 Acetic acid (1S,2R)-1-ethyl-4-oxo-4-phenyl-2-phenylsulfanyl-butyl ester 
• 139193-30-9 Acetic acid (1R,2R)-1-ethyl-4-oxo-4-phenyl-2-phenylsulfanyl-butyl ester 
• 139193-31-0 Acetic acid (1R,2S)-1-ethyl-5,5-dimethyl-4-oxo-2-phenylsulfanyl-hexyl ester 
• 139193-31-0 Acetic acid (1S,2S)-1-ethyl-5,5-dimethyl-4-oxo-2-phenylsulfanyl-hexyl ester 
• 139193-29-6 Acetic acid (1R,2S)-1-ethyl-4-oxo-2-phenylsulfanyl-hexyl ester 
• 139193-29-6 Acetic acid (1S,2S)-1-ethyl-4-oxo-2-phenylsulfanyl-hexyl ester 
• 139193-27-4 2-Acetoxy-1-chloro-1-phenylthiobutane 
• 162329-04-6 (E,1'S,3R,R_S)-3-(1'-methyl-3'-phenylsulphinyl-2'-propenyl)cyclohexan-1-one 
• 162329-01-3 (2S,R_S)-1-(phenylsulfinyl)butan-2-ol 

Relevant articles and documents

Biodegradable choline hydroxide promoted environmentally benign thiolysis of epoxides

An environmentally benign and rapid thiolysis of epoxides using a biodegradable, choline-based task-specific ionic liquid has been developed. The ring opening reaction of aryl and alkyl epoxides proceeded rapidly and afforded the corresponding β-hydroxysulfides in high yields with excellent regioselectivity. The protocol has the advantages of easy work-up, short reaction times, high yields, and a biodegradable catalyst.

Rapid, benign, and additive-free thiolysis of epoxides under ultrasonic/aqueous conditions

An environmentally friendly and efficient procedure is developed for ring opening of various epoxides with thiols under non-thermal conditions. Reactions take place by ultrasonic irradiation of the two reactants suspended in an additive-free aqueous mediu

Routes for reactions of alkylene oxides with R-β-hydroxyalkyl sulfides: Unusual exchange of functional groups

Possible routes of the previously unknown exchange reaction of alkylene oxides with R-β-hydroxyalkyl sulfides have been considered. Each route has intermediates and transition states of its own, but all the directions in the final stage lead to the formation of a single intermediate cyclic bipolar ion with intramolecular hydrogen bonding, which determines the common nature and composition of end products for all routes. The features of the reaction have been analyzed. The quantitative description of each route has been given. Pleiades Publishing, Ltd., 2012.