136964-79-9Relevant articles and documents
BIS(TERT-BUTYLSULFONYL)ACETYLENE AS A GENERAL SYNTHETIC EQUIVALENT OF ALKYNES IN DIELS-ALDER CHEMISTRY. I: HIGHLY SELECTIVE REDUCTION AND ALKYLATING MONODESULFONYLATION OF Z-1,2-BIS(TERT-BUTYLSULFONYL)ETHENES
Belloch, Jordi,Virgili, Marina,Moyano, Albert,Pericas,Miquel A.,Riera, Antoni
, p. 4579 - 4582 (2007/10/02)
Bicyclic (Z)-1,2-Bis(tert-butylsulfonyl)ethenes arising from Diels-Alder reactions of bis(tert-butylsulfonyl)acetylene are efficiently reduced to monosulfones by samarium(II) iodide and alkylatively monodesulfonylated by organolithium compounds.