136984-61-7

Basic information

• Product Name: CH₃C₆H₄NHNC(CH₃)COCH₃
• CAS NO: 136984-61-7
• Molecular Weight: 190.245
• Mol File: 136984-61-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: CH₃C₆H₄NHNC(CH₃)COCH₃(CAS DataBase Reference)
• NIST Chemistry Reference: CH₃C₆H₄NHNC(CH₃)COCH₃(136984-61-7)
• EPA Substance Registry System: CH₃C₆H₄NHNC(CH₃)COCH₃(136984-61-7)

Safety Data

• Hazardous Substances Data: 136984-61-7(Hazardous Substances Data)

Upstream product

• 140244-83-3 (Z)-(4-methylphenyl)azo tert-butyl sulfide 
• 78-93-3 butanone 
• 57573-52-1 4-methylbenzene diazonium 
• 431-03-8 dimethylglyoxal 
• 2028-84-4 p-methylbenzenediazonium chloride 
• 1522-25-4 4-hydroxy-3-methylpent-3-en-2-one 
• 637-60-5 p-tolylhydrazine hydrochloride 

Downstream Products

• 209258-03-7 [PdCl(C₁₁H₁₃N₂O)(P(C₆H₅)3)2] 
• 209258-15-1 [Pd(C₁₁H₁₂N₂O)(P(C₆H₅)3)] 
• 24006-21-1 N-methyl-N-(4-tolyl)hydrazine 
• 5705-16-8 N-benzyl-N-(p-methylphenyl)hydrazine 

Relevant articles and documents

An easy access to 2-oxohydrazones via electrophilic α-p-tolylhydrazonylation of ketone enolates with tert-butyl p-tolylazo sulfide

The title reaction conveniently furnishes, as the sole or main products, α-(p-tolylhydrazono)ketones or their N-methylderivatives (H+ or MeI quenching of the final mixture, respectively). Although the method fails with ketones having a secondary alkyl group bonded to the carbonyl, yields are otherwise more than satisfactory and particular interest is attached to the hydrazonylation of the methyl group in methyl ketones.