138691-47-1

Basic information

• Product Name: Silane, [1-(3,5-dimethyl-4-nitrophenyl)ethenyl]trimethyl-
• CAS NO: 138691-47-1
• Molecular Formula: C13H19NO2Si
• Molecular Weight: 249.385
• Mol File: 138691-47-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [1-(3,5-dimethyl-4-nitrophenyl)ethenyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [1-(3,5-dimethyl-4-nitrophenyl)ethenyl]trimethyl-(138691-47-1)
• EPA Substance Registry System: Silane, [1-(3,5-dimethyl-4-nitrophenyl)ethenyl]trimethyl-(138691-47-1)

Safety Data

• Hazardous Substances Data: 138691-47-1(Hazardous Substances Data)

Upstream product

• 81-20-9 2,6-dimethylnitrobenzene 
• 49750-22-3 1-(trimethylsilyl)vinylmagnesium bromide 

Relevant articles and documents

Reactivity of Nitro- and Nitroso-arenes with Vinyl Grignard Reagents: Synthesis of 2-(Trimethylsilyl)indoles

The reaction of nitrosoarenes and 1-(trimethylsilyl)vinylmagnesium bromide in dibutyl ether represents a useful tool for the synthesis of 2-(trimethylsilyl)indoles by cyclisation of benzene derivatives.The use of more common ethers as the solvent leads to large amounts of azo and azoxy derivatives.Conversely, the reaction of nitroarenes and 1-(trimethylsilyl)vinylmagnesium bromide gives conjugate addition products.The reasons for this behaviour are discussed.