138811-36-6

Basic information

• Product Name: 1-methyl-2,3,5-tri-O-benzyl-D-arabinofuranose
• Synonyms: 1-methyl-2,3,5-tri-O-benzyl-D-arabinofuranose
• CAS NO: 138811-36-6
• Molecular Weight: 434.532
• Mol File: 138811-36-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-methyl-2,3,5-tri-O-benzyl-D-arabinofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-2,3,5-tri-O-benzyl-D-arabinofuranose(138811-36-6)
• EPA Substance Registry System: 1-methyl-2,3,5-tri-O-benzyl-D-arabinofuranose(138811-36-6)

Safety Data

• Hazardous Substances Data: 138811-36-6(Hazardous Substances Data)

Upstream product

• 102208-53-7 (3R,4R,5R)-5-hydroxy-3,4,6-tribenzyloxy-1-hexene 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 14233-64-8 tri-O-benzyl-D-arabinolactone 
• 917-54-4 methyllithium 

Downstream Products

• 125290-97-3 7,10-Anhydro-6-deoxy-7-C-methyl-1,3,4,8,9,11-hexa-O-benzyl-D-gluco-D-lyxo-5-ulofuranose 
• 125290-97-3 7,10-Anhydro-6-deoxy-7-C-methyl-1,3,4,8,9,11-hexa-O-benzyl-D-gluco-D-lyxo-5-ulofuranose 
• 115040-65-8 2,3,5-tri-O-benzyl-1-deoxy-1-methyl-β-D-arabinofuranose 
• 115114-57-3 2,3,5-tri-O-benzyl-1-deoxy-1-methyl-α-D-arabinofuranose 
• 134001-24-4 (3R,4R,5S)-5-[(benzyloxy)methyl]-3,4-bis(phenoxymethyl)dihydrofuran-2(3H)-one 

Relevant articles and documents

Stereoselectivity in the Lewis acid mediated reduction of ketofuranoses

The Lewis acid mediated reduction of ribose-, arabinose-, xylose-, and lyxose-derived methyl and phenyl ketofuranoses with triethylsilane as nucleophile was found to proceed with good to excellent stereoselectivity to provide the 1,2-cis addition products

Synthesis of C-glycofuranosides by the stereoselective reduction of hemiacetals

Reaction of protected glycofuranolactones with organolithium reagents and reduction of the resultant hemiacetals with triethylsilane-boron trifluoride gives a stereocontrolled route to C-glycofuranosides, with hydride delivery occurring cis-to an adjacent