139017-16-6Relevant articles and documents
Asymmetric catalysis. Asymmetric catalytic intramolecular hydrosilation and hydroacylation
Barnhart, Richard W.,Wang, Xianqi,Noheda, Pedro,Bergens, Steven H.,Whelan, John,Bosnich
, p. 4335 - 4346 (2007/10/02)
Catalysts of the type [Rh(chiral diphosphine)]+ efficiently catalyse the intramolecular hydrosilation of silyl ethers derived from allylic alcohols. The products can be converted to chiral 1,3-diols. High enantiomeric excesses (ee's) are observ