139190-71-9

Basic information

• Product Name: Carbamic acid, (1-methyl-2-oxoethyl)(phenylmethyl)-, phenylmethyl ester, (S)-
• CAS NO: 139190-71-9
• Molecular Formula: C18H19NO3
• Molecular Weight: 297.354
• Mol File: 139190-71-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (1-methyl-2-oxoethyl)(phenylmethyl)-, phenylmethyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (1-methyl-2-oxoethyl)(phenylmethyl)-, phenylmethyl ester, (S)-(139190-71-9)
• EPA Substance Registry System: Carbamic acid, (1-methyl-2-oxoethyl)(phenylmethyl)-, phenylmethyl ester, (S)-(139190-71-9)

Safety Data

• Hazardous Substances Data: 139190-71-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 54159-18-1 ethyl 2-(benzylamino)propanoate 
• 100-39-0 benzyl bromide 
• 31022-10-3 N-benzyl-L-alanine methyl ester 
• 144425-57-0 Benzyl-((S)-2-hydroxy-1-methyl-ethyl)-carbamic acid benzyl ester 
• 209266-06-8 (S)-2-(Benzyl-benzyloxycarbonyl-amino)-propionic acid methyl ester 
• 139190-70-8 N-Benzyl-N-benzyloxycarbonyl-L-alanine ethyl ester 

Downstream Products

• 139190-66-2 Methyl (3S,4S)-4--3-methylpentanoate 
• 123807-64-7 (4R,5S)-1-Benzyl-4,5-dimethyl-2-pyrrolidinone 
• 497968-31-7 (1S,2S)-N-benzyl-N-[2-(5-methylfuran-2-yl)-2-hydroxy-1-methylethyl]-4-methylbenzenesulfonamide 
• 497968-33-9 (1S,2S)-N-benzyl-N-[2-(5-methylfuran-2-yl)-2-hydroxy-1-methylethyl]carbamic acid tert-butyl ester 
• 497968-38-4 (2S)-(N-benzylamino)-(1S)-(5-methylfuran-2-yl)propan-1-ol 
• 497968-32-8 (1S,2S)-N-benzyl-N-[2-(5-methylfuran-2-yl)-2-hydroxy-1-methylethyl]carbamic acid benzyl ester 
• 139190-65-1 Methyl (4S,E)-4--2-pentenoate 

Relevant articles and documents

Effective and mild method for preparation of optically active α-amino aldehydes via TEMPO oxidation

The TEMPO oxidation method is successfully applied to preparation of variously protected, optically active α-amino aldehydes without racemization and in very good yield.

Synthesis of α-amino and α-alkoxy aldehydes via oxoammonium oxidation

Oxoammonium oxidation (TEMPO, 1) of various optically active α-amino and α-alkoxy alcohols affords the corresponding aldehydes in good yield and high enantiomeric purity.