139404-87-8

Basic information

• Product Name: L-Valine, N-(phenylmethylene)-, 1,1-dimethylethyl ester, (E)-
• CAS NO: 139404-87-8
• Molecular Formula: C16H23NO2
• Molecular Weight: 261.364
• Mol File: 139404-87-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: L-Valine, N-(phenylmethylene)-, 1,1-dimethylethyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: L-Valine, N-(phenylmethylene)-, 1,1-dimethylethyl ester, (E)-(139404-87-8)
• EPA Substance Registry System: L-Valine, N-(phenylmethylene)-, 1,1-dimethylethyl ester, (E)-(139404-87-8)

Safety Data

• Hazardous Substances Data: 139404-87-8(Hazardous Substances Data)

Upstream product

• 13518-40-6 L-valine tert-butylester hydrochloride 
• 100-52-7 benzaldehyde 
• 13211-31-9 tert-butyl L-valinate 

Downstream Products

• 139404-95-8 N-<(S)-1-tert-butyloxycarbonyl-2-methylpropyl>-(5S)-5-amino-3-methoxy-5-phenyl-pent-2-enoic acid methyl ester 

Relevant articles and documents

Enantioselective Synthesis of Homoallylic Amines by Addition of Allylmetal Reagents to Imines Derived from (S)-Valine Esters

Grignard and Barbier procedures have been applied to the addition of allylmethal (Zn, Cu, Pb, Bi, Al, In) species to imines derived from (S)-valine esters, principally the methyl ester.The Zn-mediated, CeCl3- or SnCl2-catalyzed "Barbier" reactions of the