1403363-79-0Relevant articles and documents
Third-order nonlinear optical properties of unsymmetric pentamethine cyanine dyes possessing benzoxazolyl and benzothiazolyl groups
Sun, Ru,Yan, Bao-Long,Ge, Jian-Feng,Xu, Qing-Feng,Li, Na-Jun,Lu, Jian-Mei,Wu, Xing-Zhi,Song, Ying-Ling
, p. 189 - 195,7 (2020/08/20)
A series of unsymmetric pentamethine cyanine dyes featuring benzoxazolyl and benzothiazolyl groups were synthesized, the structures were characterized by 1H NMR, UV-vis absorption spectroscopy and mass spectrometry. The dyes with different anions such as chloride, tetraphenylborate and tetra(4-fluorophenyl)borate were also obtained and their solubility can be changed by the choice of the anion part. The third-order nonlinear optical properties were measured by the Z-scan technique with a picosecond laser beam at 532 nm in DMF solution. The third-order nonlinear optical susceptibilities χ(3) and the second-order hyperpolarizabilities γ' were obtained. The results reveal that these dyes exhibit strong reverse saturable absorption and nonlinear refraction.