1403767-43-0

Basic information

• Product Name: CpCr[DppNC(Me)CHC(Me)NTol](Cy)
• Synonyms: CpCr[DppNC(Me)CHC(Me)NTol](Cy)
• CAS NO: 1403767-43-0
• Molecular Weight: 547.768
• Mol File: 1403767-43-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CpCr[DppNC(Me)CHC(Me)NTol](Cy)(CAS DataBase Reference)
• NIST Chemistry Reference: CpCr[DppNC(Me)CHC(Me)NTol](Cy)(1403767-43-0)
• EPA Substance Registry System: CpCr[DppNC(Me)CHC(Me)NTol](Cy)(1403767-43-0)

Safety Data

• Hazardous Substances Data: 1403767-43-0(Hazardous Substances Data)

Upstream product

• 1403767-42-9 C₃₆H₄₃CrN₂O₃S 
• 3007-12-3 dicyclohexylmagnesium 

Downstream Products

• 1403767-41-8 C₂₉H₃₆BrCrN₂ 
• 6372-42-5 cyclohexyldiphenylphosphine 
• 1262528-70-0 [(cyclopentadienyl)Cr(III)Cl(2,6-(Me₂CH)2C₆H₃NC(Me)CH(Me)NC₆H₄Me)] 

Relevant articles and documents

Controlling secondary alkyl radicals: Ligand effects in chromium-catalyzed C-P bond formation

Chromium cyclopentadienyl β-diketiminate catalysts have been used to form Ph2PCy from Ph2PY (Y = Cl, PPh2, H) and CyX (X = Br, Cl) substrates. Manganese powder activated by PbX2 or Me3SiCl was used as the stoichiometric reductant. The Cr(III) cyclohexyl intermediate has been synthesized and structurally characterized. The observed variations in catalytic activity have been correlated with the previously observed reactivity differences imparted by modifying the N-aryl substituents on the β-diketiminate ancillary ligand.