140479-90-9

Basic information

• Product Name: tetradecyl (pentafluorophenyl)thionocarbonate
• Synonyms: tetradecyl (pentafluorophenyl)thionocarbonate
• CAS NO: 140479-90-9
• Molecular Weight: 440.518
• Mol File: 140479-90-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetradecyl (pentafluorophenyl)thionocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: tetradecyl (pentafluorophenyl)thionocarbonate(140479-90-9)
• EPA Substance Registry System: tetradecyl (pentafluorophenyl)thionocarbonate(140479-90-9)

Safety Data

• Hazardous Substances Data: 140479-90-9(Hazardous Substances Data)

Upstream product

• 112-72-1 1-Tetradecanol 
• 135192-53-9 pentafluorophenoxythiocarbonyl chloride 
• 771-61-9 2,3,4,5,6-pentafluorophenol 

Downstream Products

• 629-59-4 tetradecane 

Relevant articles and documents

The Invention of Radical Reactions. Part XXI. Simple Methods for the Radical Deoxygenation of Primary Alcohols.

Novel radical-chain deoxygenations of primary alcohols are described.The alcohols are acylated with the reagents pentafluorophenyl chlorothionoformate, 2,4,6-trichlorophenyl chlorothionoformate and 4-fluorophenyl chlorothionoformate and the intermediate thionocarbonates are deoxygenated with tributyltin hydride, triphenylsilane, diphenylsilane or phenylsilane in high-yielding reactions.Key Words: Thionocarbonates, Tributyltin hydride, Triphenylsilane, Diphenylsilane, Phenylsilane, Radical deoxygenations.