14065-22-6

Basic information

• Product Name: Benzene, 1-methoxy-2-(phenylthio)-
• CAS NO: 14065-22-6
• Molecular Formula: C13H12OS
• Molecular Weight: 216.304
• Mol File: 14065-22-6.mol
• Article Data: 86

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-2-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-2-(phenylthio)-(14065-22-6)
• EPA Substance Registry System: Benzene, 1-methoxy-2-(phenylthio)-(14065-22-6)

Safety Data

• Hazardous Substances Data: 14065-22-6(Hazardous Substances Data)

Upstream product

• 17356-93-3 2-methoxy-benzenediazonium 
• 108-98-5 thiophenol 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 873-55-2 sodium benzenesulfonate 
• 579-74-8 2-Methoxyacetophenone 
• 13513-82-1 1-(2-methoxyphenyl)ethanol 
• 882-33-7 diphenyldisulfane 
• 98-09-9 benzenesulfonyl chloride 
• 492-95-5 2-methoxyphenyldiazonium tetrafluoroborate 
• 13920-94-0 bis(2-methoxyphenyl)disulfide 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 529-28-2 4-iodoanisol 
• 3278-38-4 S-phenyl O-ethylxanthate 
• 591-50-4 iodobenzene 

Downstream Products

• 91902-74-8 1-methoxy-2-(phenylsulfinyl)benzene 
• 63212-20-4 C₁₉H₁₆ClNO₃S₂ 
• 63212-21-5 C₂₀H₁₉NO₄S₂ 
• 63212-23-7 C₂₀H₁₉NO₃S₂ 
• 63212-22-6 C₁₉H₁₇NO₃S₂ 
• 60301-04-4 2-methoxyphenyl phenyl sulfoxide 
• 60301-03-3 2-methoxyphenyl phenyl sulfoxide 
• 85021-04-1 S-(o-methoxyphenyl)-S-phenyl-N-(dichloroacetyl)sulfilimine 
• 85021-03-0 (S)-(-)-S-(o-methoxyphenyl)-S-phenyl-N-(chloroacetyl)sulfilimine 
• 59785-63-6 (S)-(-)-S-(o-methoxyphenyl)-S-phenyl-N-(trifluoroacetyl)sulfilimine 
• 23038-47-3 1-benzenesulfonyl-2-methoxy-benzene 
• 55214-86-3 2-phenylsulfanyl-phenol 

Relevant articles and documents

Environmentally Friendly and Recyclable CuCl 2-Mediated C-S Bond Coupling Strategy Using DMEDA as Ligand, Base, and Solvent

Simple reaction conditions and recyclable reagents are crucial for environmentally friendly industrial applications. An environment-friendly, recyclable and economic strategy was developed to synthesize diaryl chalcogenides by the CuCl2-catalyzed C S bondformation reaction via iodobenzenes and benzenethiols/1,2-diphenyldisulfanes using N,N'-dimethylethane-1,2-diamine (DMEDA) as ligand, base, and solvent. For these reactions, especially the reactions of diiodobenzenes and aminobenzenethiols/disulfanediyldianilines, a range of substrates are compatible and give the corresponding products in good to excellent yields. Both of the reagents in the catalytic system (CuCl2/DMEDA) are inexpensive, conveniently separable, and recyclable for more than five cycles.

Chan-Lam-Type C-S Coupling Reaction by Sodium Aryl Sulfinates and Organoboron Compounds

A Chan-Lam-Type C-S coupling reaction using sodium aryl sulfinates has been developed to provide diaryl thioethers in up to 92% yields in the presence of a copper catalyst and potassium sulfite. Both electron-rich and electron-poor sodium aryl sulfinates and diverse organoboron compounds were tolerated for the synthesis of aryl and heteroaryl thioethers and dithioethers. The mechanistic study suggested that potassium sulfite was involved in the deoxygenation of sulfinate through a radical process.

Synthesis of diaryl sulfides based on copper-doped OMS-2

We describe a practical protocol for efficiently preparing diaryl sulfide compounds using Cu–OMS-2 as the catalyst. Cu–OMS-2 originates from manganese oxide octahedral molecular sieves modified with copper ions and catalyzes the C–S coupling reaction of substituted thiophenols and aryl halides. This protocol has the advantages of environmental friendliness, simple operation, high yields, good tolerance of functional groups, and the Cu–OMS-2 catalytic material can be recycled several times.