141311-38-8

Basic information

• Product Name: Benzoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-5-hydroxy-, methyl ester
• CAS NO: 141311-38-8
• Molecular Formula: C13H17NO5
• Molecular Weight: 267.282
• Mol File: 141311-38-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-5-hydroxy-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-5-hydroxy-, methyl ester(141311-38-8)
• EPA Substance Registry System: Benzoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-5-hydroxy-, methyl ester(141311-38-8)

Safety Data

• Hazardous Substances Data: 141311-38-8(Hazardous Substances Data)

Upstream product

• 4248-19-5 tert-butyl carbazate 
• 618-89-3 methyl 3-bromobenzoate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 67973-80-2 3-amino-5-hydroxy-benzoic acid methyl ester 

Downstream Products

• 875439-61-5 3-tert-butoxycarbonylamino-5-(tert-butyl-diphenylsilanyloxy)-benzyl bromide 
• 875439-70-6 3-tert-butoxycarbonylamino-5-(tert-butyl-diphenylsilanyloxy)-benzyl alcohol 
• 875439-69-3 3-tert-butoxycarbonylamino-5-(tert-butyl-diphenylsilanyloxy)-benzoic acid methyl ester 

Relevant articles and documents

Aromatic borylation/amidation/oxidation: A rapid route to 5-substituted 3-amidophenols

5-Substituted 3-amidophenols are prepared by subjecting 3-substituted halobenzenes to an Ir-catalyzed aromatic borylation, followed by a Pd-catalyzed amidation, and finally an oxidation of the boronic ester intermediate. The entire C-H activation borylation/amidation/oxidation sequence can be accomplished without isolation of any intermediate arenes. Usefully, amide partners can include lactams, carbamates, and ureas.