14155-23-8 Usage
Description
METHYL 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE is a white crystalline solid that is utilized in the field of organic chemistry, particularly for the selective α-D-glucosylation of methyl 4,6-O-benzylidene-αand -β-D-glucopyranosides. METHYL 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE is significant due to its unique chemical properties and potential applications in various industries.
Uses
Used in Organic Chemistry:
METHYL 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE is used as a key compound for the selective α-D-glucosylation of methyl 4,6-O-benzylidene-αand -β-D-glucopyranosides. This application is crucial in the synthesis of complex carbohydrate structures and the development of new bioactive molecules with potential pharmaceutical and chemical applications.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, METHYL 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE is used as a building block for the development of novel drug candidates. Its unique structure allows for the creation of new molecules with potential therapeutic properties, contributing to the advancement of drug discovery and development.
Used in Chemical Research:
METHYL 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE is also used in chemical research as a model compound for studying the properties and reactivity of similar carbohydrate derivatives. This helps researchers gain a deeper understanding of the chemical behavior of these compounds and their potential applications in various fields.
Used in Material Science:
In the field of material science, METHYL 4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSIDE can be used as a component in the development of new materials with specific properties, such as improved biocompatibility or enhanced chemical stability. This can lead to the creation of innovative materials for various applications, including medical devices and advanced materials for industrial use.
Check Digit Verification of cas no
The CAS Registry Mumber 14155-23-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,1,5 and 5 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 14155-23:
(7*1)+(6*4)+(5*1)+(4*5)+(3*5)+(2*2)+(1*3)=78
78 % 10 = 8
So 14155-23-8 is a valid CAS Registry Number.
InChI:InChI=1/C14H18O6/c1-17-14-11(16)10(15)12-9(19-14)7-18-13(20-12)8-5-3-2-4-6-8/h2-6,9-16H,7H2,1H3/t9-,10-,11-,12-,13?,14-/m1/s1
14155-23-8Relevant articles and documents
Kondo
, p. 386,388 (1973)
A practical synthesis of methyl 4,6-O-benzylidene-α- and β-D-glucopyranoside
Hall, David M.
, p. 158 - 160 (1980)
-
Exploration of the Fluoride Reactivity of Aryltrifluoroborate on Selective Cleavage of Diphenylmethylsilyl Groups
Fujiki, Katsumasa,Tanaka, Katsunori
supporting information, p. 4616 - 4620 (2020/07/06)
The first known report on the fluoride catalytic reactivity of potassium aryltrifluoroborate is described. The fluoride reactivity of phenyltrifluoroborate was controlled by substituents on the trifluoroborate-attached benzene, such as the methoxy group a
Conformational analysis of the disaccharide methyl a-d-mannopyranosyl-(1→3)-2-O-acetyl-β-D-manno-pyranoside monohydrate
Zhang, Wenhui,Wu, Qingquan,Oliver, Allen G.,Serianni, Anthony S.
, p. 610 - 615 (2019/06/14)
The crystal structure of methyl β-d-mannopyranosyl-(1→3)-2-O-acetyl-β-d-mannopyranoside monohydrate, C15H26O12.H2O, (II), has been determined and the structural parameters for its constituent β-d-mannopyranosyl residue compared with those for methyl β-d-mannopyranoside. Mono-O-acetylation appears to promote the crystallization of (II), inferred from the difficulty in crystallizing methyl β-d-mannopyranosyl-(1→3)-β-d-mannopyranoside despite repeated attempts. The conformational properties of the O-acetyl side chain in (II) are similar to those observed in recent studies of peracetylated mannose-containing oligosaccharides, having a preferred geometry in which the C2—H2 bond eclipses the C O bond of the acetyl group. The C2—O2 bond in (II) elongates by ≈0.02 ? upon O-acetylation. The phi (φ) and psi () torsion angles that dictate the conformation of the internal O-glycosidic linkage in (II) are similar to those determined recently in aqueous solution by NMR spectroscopy for unacetylated (II) using the statistical program MA'AT, with a greater disparity found for (? = ≈16°) than for φ (? = ≈6°).