1416982-07-4

Basic information

• Product Name: 1-(4-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate
• Synonyms: 1-(4-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate
• CAS NO: 1416982-07-4
• Molecular Weight: 329.34
• Mol File: 1416982-07-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate(1416982-07-4)
• EPA Substance Registry System: 1-(4-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate(1416982-07-4)

Safety Data

• Hazardous Substances Data: 1416982-07-4(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 50-00-0 formaldehyd 
• 2393-23-9 4-methoxy-benzylamine 
• 333-27-7 methyl trifluoromethanesulfonate 
• 15175-54-9 N,N-dimethyl-4-methoxylbenzylamine 

Downstream Products

• 726-18-1 4,4'-dianisylmethane 
• 55164-80-2 3-(4-methoxy-phenyl)quinolin-2(1H)-one 
• 58680-51-6 1-methoxy-4-(tosylmethyl)benzene 
• 62212-22-0 1,2-bis(4-methoxybenzyl)diselane 
• 16384-66-0 3-(4-methoxyphenyl)-1,2-diphenylpropan-1-one 
• 349627-93-6 2-(4-methoxyphenyl)-N-(p-tolyl)acetamide 
• 18255-07-7 1-methoxy-4-<(phenylseleno)methyl>benzene 
• 55539-39-4 p-methoxybenzylphenylsulfone 
• 834-14-0 p-benzylanizole 
• 52126-09-7 4-(4-methoxyphenylmethyl)benzonitrile 
• 37985-01-6 (E)-1-methoxy-4-(4-phenylbut-2-en-1-yl)benzene 
• 167688-16-6 1-methoxy-4-(3-phenylprop-2-yn-1-yl)benzene 
• 16114-90-2 <(4-methoxyphenyl)methyl>diphenylphosphine oxide 
• 74384-21-7 phenyl 2-(4-(methoxy)phenyl)acetate 

Relevant articles and documents

Palladium-Catalyzed C-N Cross-Coupling of NH-Heteroarenes and Quaternary Ammonium Salts via C-N Bond Cleavage

In this paper, we extend the substrate class of Buchwald-Hartwig amination to quaternary ammonium salts. In the presence of Pd(OAc)2 and t-BuXPhos, the coupling of aryl- or arylmethyltrimethylammonium triflates with NH-heteroarenes via C-N bond cleavage affords the desired N-aryl or N-arylmethyl heteroarenes in moderate to excellent yields.

Synthesis of Dibenzylic Diselenides from Elemental Selenium and Benzylic Quaternary Ammonium Salts

Abstract: Substituted dibenzyl diselenides are synthesized in good yields (74–91 %) by SN2 nucleophilic substitution of benzylic trimethylammonium salts and diselenide dianion (Se2?), in situ generated from elemental selenium, under

Transition metal-free coupling reactions of benzylic trimethylammonium salts with di(hetero)aryl disulfides and diselenides

A new protocol was developed to synthesize (enantioenriched) thioethers and selenoethers from (chiral) benzylic trimethylammonium salts and di(hetero)aryl disulfides or diselenides. These syntheses were promoted by the presence of weak base and did not require the use of any transition metal, and resulted in the target products with good to excellent yields (72-94%). Using quaternary ammonium salts synthesized from enantiomerically enriched amines led to highly enantiopure benzylic thioethers and selenoethers (94-99% ee) with configurations reversed from those of their enantioenriched quaternary ammonium salts. This journal is