141983-21-3Relevant articles and documents
Studies on Selective Nucleophilic Substitution Reactions of + PF6- Complexes (M = Fe, Ru)
Pearson, Anthony J.,Park, Jewn G.,Zhu, Ping Y.
, p. 3583 - 3589 (2007/10/02)
Reactions of + PF6- complexes (M = Fe, Ru) with phenoxide nucleophiles were found to proceed with excellent selectivity under mild conditions to give products of monosubstitution.Using aminophenoxides, a preference for O-arylation was observed, while amino alcohols such as prolinol react selectively on nitrogen.Methodology for sequential selective displacement of both chlorides by different nucleophiles is reported.