1421692-00-3

Basic information

• Product Name: (3-(1-(tert-butyldimethylsilylimino)prop-1-en-2-yl)phenyl)(phenyl)methanone
• Synonyms: (3-(1-(tert-butyldimethylsilylimino)prop-1-en-2-yl)phenyl)(phenyl)methanone
• CAS NO: 1421692-00-3
• Molecular Weight: 349.548
• Mol File: 1421692-00-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3-(1-(tert-butyldimethylsilylimino)prop-1-en-2-yl)phenyl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3-(1-(tert-butyldimethylsilylimino)prop-1-en-2-yl)phenyl)(phenyl)methanone(1421692-00-3)
• EPA Substance Registry System: (3-(1-(tert-butyldimethylsilylimino)prop-1-en-2-yl)phenyl)(phenyl)methanone(1421692-00-3)

Safety Data

• Hazardous Substances Data: 1421692-00-3(Hazardous Substances Data)

Upstream product

• 42872-30-0 alpha-(m-benzoylphenyl)propionitrile 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1421692-22-9 (S)-2-(3-benzoylphenyl)propanenitrile 
• 161527-65-7 (2R)-[3-(phenylcarbonyl)phenyl]propanenitrile 

Relevant articles and documents

Catalytic asymmetric protonation of silyl ketene imines

An efficient catalytic and highly enantioselective protonation of silyl ketene imines is described. The reaction is catalyzed by the chiral phosphoric acids TRIP or STRIP in the presence of a stoichiometric amount of methanol as the proton source and silyl acceptor. A variety of substituted racemic silyl ketene imines have been transformed into highly enantioenriched nitriles.