1425647-29-5

Basic information

• Product Name: (E)-1-(3,3,3-trifluoroprop-1-enyl)-3-tert-butoxycarbonylaminobenzene
• Synonyms: (E)-1-(3,3,3-trifluoroprop-1-enyl)-3-tert-butoxycarbonylaminobenzene
• CAS NO: 1425647-29-5
• Molecular Weight: 287.282
• Mol File: 1425647-29-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-(3,3,3-trifluoroprop-1-enyl)-3-tert-butoxycarbonylaminobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(3,3,3-trifluoroprop-1-enyl)-3-tert-butoxycarbonylaminobenzene(1425647-29-5)
• EPA Substance Registry System: (E)-1-(3,3,3-trifluoroprop-1-enyl)-3-tert-butoxycarbonylaminobenzene(1425647-29-5)

Safety Data

• Hazardous Substances Data: 1425647-29-5(Hazardous Substances Data)

Upstream product

• 380430-68-2 3-(tert-butoxycarbonylamino)phenylboronic acid 
• 102687-65-0 trans-1-chloro-3,3,3-trifluoropropene 
• 1425647-72-8 tert-butyl (E)-(3-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)vinyl)phenyl)carbamate 
• 185619-66-3 (3-ethynyl-phenyl)-carbamic acid tert-butyl ester 
• 887144-94-7 Togni's reagent II 

Relevant articles and documents

MONOSUBSTITUTED(FLUOROALKYL)ETHYLENES AND METHOD OF PRODUCING THE SAME

PROBLEM TO BE SOLVED: To provide a method of efficiently producing monosubstituted(fluoroalkyl)ethylenes. SOLUTION: The method comprises reacting a 1-chloro-2-(fluoroalkyl)ethylene with an organoboron compound under coexistence of an alkylphosphine coordinated palladium catalyst, an alkali metal salt and water so as to obtain a monosubstituted(fluoroalkyl)ethylene represented by the general formula (5). (In the formula, R represents a naphthalene-1-yl group or the like, and Rf represents C1-4 fluoroalkyl group.) SELECTED DRAWING: None COPYRIGHT: (C)2017,JPO&INPIT