14276-84-7Relevant articles and documents
Carbon dioxide as a C1 building block for the formation of carboxylic acids by formal catalytic hydrocarboxylation
Ostapowicz, Thomas G.,Schmitz, Marc,Krystof, Monika,Klankermayer, Juergen,Leitner, Walter
, p. 12119 - 12123 (2013/12/04)
A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO2, and H2. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water-gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst (see scheme). Copyright
CARBONYLATION OF OLEFINS AND ALCOHOLS AT ATMOSPHERIC PRESSURE IN THE PRESENCE OF ACID CATALYSTS WITH ADDED Ag2O OR Cu2O
Pirozhkov, S. D.,Stepanyan, A. S.,Myshenkova, T. N.,Ordyan, M. B.,Lapidus, A. L.
, p. 1852 - 1858 (2007/10/02)
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