14289-95-3

Basic information

• Product Name: Benzene, [3-(1-methylethoxy)-1-propenyl]-, (E)-
• CAS NO: 14289-95-3
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 14289-95-3.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, [3-(1-methylethoxy)-1-propenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [3-(1-methylethoxy)-1-propenyl]-, (E)-(14289-95-3)
• EPA Substance Registry System: Benzene, [3-(1-methylethoxy)-1-propenyl]-, (E)-(14289-95-3)

Safety Data

• Hazardous Substances Data: 14289-95-3(Hazardous Substances Data)

Upstream product

• 300-57-2 allylbenzene 
• 67-63-0 isopropyl alcohol 
• 4392-24-9 Cinnamyl bromide 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 82859-39-0 trans-cinnamyl iodide 
• 939-48-0 isopropyl benzoate 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 2327-99-3 1-phenylpropadiene 
• 10147-11-2 propargyl benzene 
• 673-32-5 1-Phenylprop-1-yne 
• 21040-45-9 Cinnamyl acetate 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 23250-03-5 β-hydroxyethyltriphenylphosphonium chloride 
• 100-52-7 benzaldehyde 

Downstream Products

• 36004-04-3 ethyl (E)-1-phenylbut-1-en-3-ol 
• 14371-10-9 (E)-3-phenylpropenal 
• 58506-33-5 5-phenyl-trans,trans-2,4-pentadien-1-ol 
• 38447-05-1 (2E,4E)-methyl 5-phenylpenta-2,4-dienoate 
• 24808-74-0 (E)-(3-methoxybut-1-en-1-yl)benzene 
• 112655-08-0 ((1E,3E)-5-methoxypenta-1,3-dien-1-yl)benzene 
• 1896-62-4 (E)-benzalacetone 
• 13466-40-5 (2E, 4E)-5-phenylpenta-2,4-dienal 

Relevant articles and documents

MERCURY(II) OXIDE/TETRAFLUOROBORIC ACID. AN UNUSUAL BEHAVIOR IN THE OXIDATION OF ALKENES. SYNTHESIS OF trans-CINNAMYLETHERS

The synthesis of trans-cinnamylethers by oxidation of allylbenzene is described.The reaction cannot be explained by formation of an allylic mercurial.A new type of mechanism in the oxidation of alkenes by mercury(II) salts is proposed.

Oxidative cleavage of allyl ethers by an oxoammonium salt

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.

Regio- and stereoselective Au(I)-catalyzed intermolecular hydroalkoxylation of aryl allenes

In the presence of a catalytic amount of Ph3PAuNO3 and H2SO4, the hydroalkoxylation of allenes with alcohols has been shown to proceed smoothly and give allylic ethers in good yields and high regio- and stereoselectivity. Georg Thieme Verlag Stuttgart.