1430197-49-1

Basic information

• Product Name: N^δ-(2,3,5-tri-O-benzyl-α-D-ribosyl)-N^α-benzyloxycarbonylglutamine benzyl ester
• CAS NO: 1430197-49-1
• Molecular Weight: 772.895
• Mol File: 1430197-49-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N^δ-(2,3,5-tri-O-benzyl-α-D-ribosyl)-N^α-benzyloxycarbonylglutamine benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N^δ-(2,3,5-tri-O-benzyl-α-D-ribosyl)-N^α-benzyloxycarbonylglutamine benzyl ester(1430197-49-1)
• EPA Substance Registry System: N^δ-(2,3,5-tri-O-benzyl-α-D-ribosyl)-N^α-benzyloxycarbonylglutamine benzyl ester(1430197-49-1)

Safety Data

• Hazardous Substances Data: 1430197-49-1(Hazardous Substances Data)

Upstream product

• 95700-16-6 benzyl 5-amino-2-(((benzyloxy)carbonyl)amino)-5-oxopentanoate 

Relevant articles and documents

Stereoselective ribosylation of amino acids

The glycosylation properties of ribofuranosyl N-phenyltrifluoroacetimidates toward carboxamide side chains of asparagine and glutamine were investigated. Conditions were found that promote nearly exclusive formation of the α-anomerically configured N-glycosides. The strategy allows for the synthesis of Fmoc-amino acids suitably modified for the preparation of ADP-ribosylated peptides. Furthermore, ribosylation of serine with these donors proved to be completely α-selective, and for the first time, α-ribosylated glutamic and aspartic acid, the naturally occurring sites for poly-ADP-ribosylation, were synthesized.