143192-61-4Relevant articles and documents
Synthesis of tetracyclic chromenones via platinum(ii) chloride catalysed cascade cyclization of enediyne-enones
Sivaraman, Mahalingam,Perumal, Paramasivan T.
supporting information, p. 1318 - 1327 (2014/03/21)
PtCl2 catalysed cascade cyclization of an enediyne-enone system to afford a tetracyclic chromenone is reported, which proceeds through two consecutive highly regioselective 6-endo-dig cyclizations in a single step with the formation of two new C-C bonds and two new rings in excellent yield. A mechanism for this transformation is proposed based on the isolated intermediates.
Highly Unsaturated Oligomeric Hydrocarbons: α-(Phenylethynyl)-ω-phenylpoly
Grubbs, Robert H.,Kratz, Detlef
, p. 149 - 158 (2007/10/02)
A new set of conjugated oligomers C6H5CC-(1,2-C6H4CC)n-C6H5 (10; n=3-7) comprised of acetylene and phenyl units linked together at the 1,2 positions of the aromatic ring is introduced.The facile synthesis of these compounds is achieved through the Pd-medi