14323-06-9

Basic information

• Product Name: Tris(2,2'-bipyridine)ruthenium dichloride
• Synonyms: 2,2'-BIPYRIDINE RUTHENOUS DICHLORIDE;RUTHENIUM TRIS (2,2'-BIPYRIDYL)CHLORIDE;TRIS(2,2'-BIPYRIDINE) RUTHENIUM (II) CHLORIDE;tris(2,2’-bipyridine-n,n’)-,dichloride,(oc-6-11)-ruthenium(2++;tris[2,2'-bipyridine]ruthenium dichloride;Ru(phen)3Cl2;2,2''-Bipyridyl ruthenous dichloride;Nsc71326
• CAS NO: 14323-06-9
• Molecular Formula: C30H24Cl2N6Ru
• Molecular Weight: 640.53
• EINECS: 238-266-7
• Product Categories: electronic
• Mol File: 14323-06-9.mol
• Article Data: 0

Chemical Properties

• Boiling Point: 272.5 °C at 760 mmHg
• Flash Point: 107.2 °C
• Appearance: /
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• CAS DataBase Reference: Tris(2,2'-bipyridine)ruthenium dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: Tris(2,2'-bipyridine)ruthenium dichloride(14323-06-9)
• EPA Substance Registry System: Tris(2,2'-bipyridine)ruthenium dichloride(14323-06-9)

Safety Data

• Hazardous Substances Data: 14323-06-9(Hazardous Substances Data)

Usage

Description

Tris(2,2'-bipyridine)ruthenium dichloride, also known as Ru(bpy)?2?, is a coordination compound consisting of a ruthenium(II) center coordinated to three 2,2'-bipyridine ligands. It is a highly stable and well-studied complex, known for its unique photophysical and electrochemical properties.

Uses

Used in Photochemical Applications:
Tris(2,2'-bipyridine)ruthenium dichloride is used as a photosensitizer for the preparation of expanded microspheres under normal pressure induced by visible light. Its strong absorption in the visible region and efficient charge transfer properties make it an ideal candidate for photochemical reactions, enabling the expansion of microspheres without the need for high pressure or extreme conditions.
Used in Analytical Chemistry:
In analytical chemistry, Tris(2,2'-bipyridine)ruthenium dichloride is used as a luminescent probe for the detection of various analytes, such as metal ions, anions, and biomolecules. Its strong luminescence upon interaction with target molecules allows for sensitive and selective detection, making it a valuable tool in analytical applications.
Used in Solar Energy Conversion:
Due to its favorable redox properties and light absorption characteristics, Tris(2,2'-bipyridine)ruthenium dichloride is used as a component in dye-sensitized solar cells (DSSCs). It serves as a sensitizer that absorbs sunlight and injects electrons into the conduction band of the semiconductor, contributing to the overall efficiency of the solar cell.
Used in Catalysts:
Tris(2,2'-bipyridine)ruthenium dichloride is also employed as a catalyst in various chemical reactions, such as oxidation and reduction processes. Its ability to undergo reversible redox reactions and stabilize reactive intermediates makes it a useful catalyst for promoting specific chemical transformations.