14331-64-7Relevant articles and documents
Recyclization of 1,3,4-oxadiazoles and bis-1,3,4-oxadiazoles into 1,2,4-triazole derivatives. Synthesis of 5-unsubstituted 1,2,4-triazoles
Korotkikh,Kiselev,Knishevitsky,Raenko,Pekhtereva,Shvaika
, p. 866 - 871 (2005)
Efficient methods have been developed for obtaining precursors of stable carbenes, viz. 5-unsubstituted 3,4-diaryl-1,2,4-triazoles and 3,3′- or 4,4′-bridge linked bis-1,2,4-triazoles, by the recyclization of 5-unsubstituted 1,3,4-oxadiazoles or p-phenylen
Two green iridium(iii) complexes containing the electron-transporting group of 4-phenyl-4H-1,2,4-triazole for highly efficient OLEDs
Lu, Guang-Zhao,Liu, Liang,Tu, Zhen-Long,Zhou, Yong-Hui,Zheng, You-Xuan
, p. 2022 - 2028 (2019/02/24)
Two new iridium(iii) cyclometalated complexes (Ir-TN3T and Ir-TN4T) with 2′,6′-bis(trifluoromethyl)-2,3′-bipyridine (TN3T) and 2′,6′-bis(trifluoromethyl)-2,4′-bipyridine (TN4T) as the cyclometalated ligands and
Tunable protic ionic liquids as solvent-catalysts for improved synthesis of multiply substituted 1,2,4-triazoles from oxadiazoles and organoamines
Chen, Xiaofeng,Liu, Rui,Xu, Yuan,Zou, Gang
experimental part, p. 4813 - 4819 (2012/07/31)
More than green alternatives to traditional volatile molecular organic solvents, protic ionic liquids as dual solvent-catalysts have been successfully used to promote reactions of organoamines with oxadiazoles to afford sterically hindered 1,2,4-triazoles. Among the tested protic ionic liquids, pyridinium trifluoroacetate and acetate showed the highest efficiency for the reactions of arylamines and alkylamines, respectively, indicating that tunable catalysis could be readily effected with protic ionic liquid solvent-catalysts by simply tuning their cation and anion counterparts. A general and efficient approach has been developed for synthesis of multiply substituted 1,2,4-triazoles based on the tunable protic ionic liquid solvent-catalyst systems.