1435657-98-9

Basic information

• Product Name: diethyl 2,2′-5′,2′′-terthiophene-4,4′′-bis(p-tolyl)-5,5′′-dicarboxylate
• CAS NO: 1435657-98-9
• Molecular Weight: 572.77
• Mol File: 1435657-98-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl 2,2′-5′,2′′-terthiophene-4,4′′-bis(p-tolyl)-5,5′′-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2,2′-5′,2′′-terthiophene-4,4′′-bis(p-tolyl)-5,5′′-dicarboxylate(1435657-98-9)
• EPA Substance Registry System: diethyl 2,2′-5′,2′′-terthiophene-4,4′′-bis(p-tolyl)-5,5′′-dicarboxylate(1435657-98-9)

Safety Data

• Hazardous Substances Data: 1435657-98-9(Hazardous Substances Data)

Upstream product

• 19948-62-0 1,1'-di-p-tolyl-3,3'-thiophene-2,5-diyl-bis-propenone 
• 623-51-8 ethyl 2-sulfanylacetate 
• 79109-69-6 2,5-bis-(trimethylsilyl)ethynylthiophene 
• 79109-72-1 2,5-diethynylthiophene 

Relevant articles and documents

Efficient pseudo-five-component coupling-Fiesselmann synthesis of luminescent oligothiophenes and their modification

(Hetero)aryl bis-acid chlorides and terminal alkynes, or likewise acid chlorides and terminal dialkynes, and ethyl 2-mercaptoacetate can be reacted to give highly luminescent symmetrical terthiophenes and quinquethiophenes in the sense of a consecutive pseudo-five-component reaction in good to excellent yields. Further functionalization of the obtained oligomers can be readily achieved by halogenation followed by a metal-catalyzed coupling reaction to give α,ω-diester substrates for subsequent transformations into highly functionalized materials. The Royal Society of Chemistry.