144008-26-4

Basic information

• Product Name: Propanoic acid, 3,3,3-trifluoro-2-[(4-methoxyphenyl)imino]-, phenylmethyl ester
• CAS NO: 144008-26-4
• Molecular Formula: C17H14F3NO3
• Molecular Weight: 337.298
• Mol File: 144008-26-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Propanoic acid, 3,3,3-trifluoro-2-[(4-methoxyphenyl)imino]-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanoic acid, 3,3,3-trifluoro-2-[(4-methoxyphenyl)imino]-, phenylmethyl ester(144008-26-4)
• EPA Substance Registry System: Propanoic acid, 3,3,3-trifluoro-2-[(4-methoxyphenyl)imino]-, phenylmethyl ester(144008-26-4)

Safety Data

• Hazardous Substances Data: 144008-26-4(Hazardous Substances Data)

Upstream product

• 1039136-54-3 2-(trimethylsilyl)ethyl (E)-3,3,3-trifluoro-2-(4-methoxyphenylimino)propanoate 
• 100-39-0 benzyl bromide 
• 75999-66-5 (Z)-2,2,2-trifluoro-N-(4-methoxyphenyl)acetimidoyl chloride 
• 201230-82-2 carbon monoxide 
• 134481-27-9 N-(p-Anisyl)-2,2,2-trifluoroacetimidoyl iodide 
• 100-51-6 benzyl alcohol 

Downstream Products

• 1051442-86-4 benzyl 2-[(4-methoxyphenyl)(trimethylsilyl)amino]-2-(trifluoromethyl)-3-butenoate 
• 17463-43-3 3,3,3-trifluoro-DL-alanine 
• 422-23-1 2-(trifluoromethyl)alanine 
• 127127-26-8 2-(trifluoromethyl)norleucine 

Relevant articles and documents

Selective formal transesterification of fluorinated 2-(trimethylsilyl)ethyl α-imino esters mediated by TBAF

(Chemical Equation Presented) The scope of the transesterification reaction between β-fluorinated α-imino esters and various electrophiles in the presence of TBAF as fluorine source is described. The reaction is highly selective for alkyl iodides, bromide

Homologation of trifluoroacetimidoyl iodides by palladium-catalyzed carbonylation. An approach to α-amino perfluoroalkanoic acids

Homologation of trifluoroacetimidoyl iodides and the related perfluoro-compounds by palladium-catalyst under CO(1atm)-atmosphere in the presence of alcohols gives α-imino perfluoroalkanoates which are transformed to α-amino perfluoroalkanoic acids.