144261-46-1

Basic information

• Product Name: 2-Propenoic acid (3-methoxyphenyl)methyl ester
• Synonyms: 3-(4-METHOXYPHENYL)-2-PROPENOIC ACID METHYL ESTER;4-METHOXYCINNAMIC ACID METHYL ESTER;METHYL P-METHOXYCINNAMATE;METHYL 4-METHOXYCINNAMATE;SPECS AE-641/05563005;P-MethoxylMethylCinnamate;P-MethoxylCinnamaldehydeIsooctyl;p-Methoxyl
• CAS NO: 144261-46-1
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.21
• EINECS: 1533716-785-6
• Mol File: 144261-46-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 276 °C
• Flash Point: 110 °C
• Appearance: /
• Density: 1.080
• Vapor Pressure: 0.00499mmHg at 25°C
• Refractive Index: 1.51
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2-Propenoic acid (3-methoxyphenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid (3-methoxyphenyl)methyl ester(144261-46-1)
• EPA Substance Registry System: 2-Propenoic acid (3-methoxyphenyl)methyl ester(144261-46-1)

Safety Data

• Hazardous Substances Data: 144261-46-1(Hazardous Substances Data)

Usage

Chemical Properties

White crystalline solid

InChI:InChI=1/C11H12O3/c1-3-11(12)14-8-9-5-4-6-10(7-9)13-2/h3-7H,1,8H2,2H3

Upstream product

• 6971-51-3 3-methoxybenzyl alcohol 
• 814-68-6 acryloyl chloride 

Downstream Products

• 144261-64-3 3-phenyl-3-hydroxy-2-methylene-propanoic acid m-methoxybenzyl ester 

Relevant articles and documents

Ruthenium(II)-Catalyzed Highly Chemo- And Regioselective Oxidative C6 Alkenylation of Indole-7-carboxamides

We disclosed the first efficient method for highly chemo- and regioselective C6 alkenylation of indole-7-carboxamides using inexpensive Ru(II) catalyst through chelation assisted C-H bond activation. Electronically diverse indole-7-carboxamides and alkenes react efficiently to produce a wide range of C6 alkenyl indole derivatives. Further the C6 alkenyl indole-7-carboxamides modified to their derivatives through simple chemical transformations. The observed regioselectivity and kinetics has been evidenced by deuterium incorporation and intermolecular competitive studies. In addition, for mechanistic insights, the intermediates were analyzed by HRMS.

The 'Baylis - Hillman reaction' mechanism and applications revisited

It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.