14479-58-4

Basic information

• Product Name: 2-Propenoic acid, 2-cyano-3-(4-methoxyphenyl)-, methyl ester, (E)-
• Synonyms: METHYL (E)-2-CYANO-3-(4-METHOXYPHENYL)ACRYLATE;methyl 2-cyano-3-(4-methoxyphenyl)acrylate
• CAS NO: 14479-58-4
• Molecular Formula: C12H11NO3
• Molecular Weight: 217.224
• Mol File: 14479-58-4.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-cyano-3-(4-methoxyphenyl)-, methyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-cyano-3-(4-methoxyphenyl)-, methyl ester, (E)-(14479-58-4)
• EPA Substance Registry System: 2-Propenoic acid, 2-cyano-3-(4-methoxyphenyl)-, methyl ester, (E)-(14479-58-4)

Safety Data

• Hazardous Substances Data: 14479-58-4(Hazardous Substances Data)

Usage

Commonly known as

Methyl 3-(4-methoxyphenyl)-2-cyanoacrylate

Physical properties

Colorless liquid with a fruity odor

Use

Adhesive in various industrial and commercial applications

Bonding properties

Fast-curing and strong bonding

Materials bonded

Plastic, rubber, metal

Safety precautions

Handle with caution, can cause skin and eye irritation, harmful if inhaled or ingested

Versatility

Wide range of practical applications

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 105-34-0 methyl 2-cyanoacetate 
• 768-60-5 4-methoxyphenylacetylen 
• 7677-24-9 trimethylsilyl cyanide 
• 7515-17-5 methyl 3-(4-methoxyphenyl)propynoate 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 372-09-8 cyanoacetic acid 
• 15795-54-7 5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione 

Downstream Products

• 1646852-29-0 methyl 2-cyano-2-(4-methoxybenzyl)pent-4-enoate 
• 1010458-25-9 C₁₈H₁₇NO₃ 
• 75140-48-6 methyl 2-cyano-3-(4-methoxyphenyl)propionate 
• 113966-61-3 (E)-2-Methoxycarbonyl-3-(4-methoxyphenyl)oxirane-2-carbonitrile 
• 117918-97-5 methyl (E)-2-cyano-4-phenyl-4-(p-methoxyphenyl)-2-pentenoate 
• 117918-98-6 trans-1-cyano-1-(methoxycarbonyl)-2-methyl-2-phenyl-3-(p-methoxyphenyl)cyclopropane 

Relevant articles and documents

5-arylidene derivatives of meldrum's acid as synthons in pyrano[4,3-b]pyran synthesis

The reactions of 5-arylidene derivatives of Meldrum's acid with ethyl vinyl ether or N-vinyl-2-oxazolidinone yielded trans-trans-(2,4:4,7)-pyrano[4,3-b] pyrans, cis-trans-(2,4:4,7)-pyrano[4,3-b]pyrans, or diastereoisomeric mixtures of pyrano[4,3-b]pyrans

Aza-Wittig Reaction with Nitriles: How Carbonyl Function Switches from Reacting to Activating

Transformations of α-EWG-substituted (electron-withdrawing group, EWG) γ-azidobutyronitriles proceeding via unusual aza-Wittig reactions between the phosphazene and nitrile functions and affording pyrrole-derived iminophosphazenes were developed. α-EWGs w

Knoevenagel condensation catalyzed by novel Nmm-based ionic liquids in water

A series of novel N-methyl morpholine (Nmm) based ionic liquids with 1,2-propanediol group were synthesized and used as catalysts for Knoevenagel condensation at room temperature in water. Under the effect of the catalyst, various aldehydes or aliphatic ketones could react with a wide range of activated methylene compounds well, including malononitrile, alkyl cyanoacetate, cyanoacetamide, β-diketone, barbituric acid, 2-arylacetonitrile and thiazolidinedione. Furthermore, most of the products could be separated just by filtrating and washing with water. Additionally, the catalyst is recyclable and applicable for the large-scale synthesis.