145804-82-6

Basic information

• Product Name: 2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol
• Synonyms: 2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol
• CAS NO: 145804-82-6
• Molecular Weight: 274.317
• Mol File: 145804-82-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol(145804-82-6)
• EPA Substance Registry System: 2-(2,6-dimethoxyphenoxy)-1-phenylethan-1-ol(145804-82-6)

Safety Data

• Hazardous Substances Data: 145804-82-6(Hazardous Substances Data)

Upstream product

• 91-10-1 1,3-dimethoxy-2-hydroxy-benzene 
• 70-11-1 α-bromoacetophenone 
• 19514-00-2 α-(2,6-dimethoxy)-phenoxyacetophenone 
• 140455-39-6 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethan-1-one 

Downstream Products

• 91-10-1 1,3-dimethoxy-2-hydroxy-benzene 
• 98-86-2 acetophenone 
• 98-85-1 1-Phenylethanol 
• 1193-81-3 rac-1-cyclohexylethanol 
• 140455-39-6 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethan-1-one 
• 100-42-5 styrene 
• 100-41-4 ethylbenzene 
• 65-85-0 benzoic acid 
• 17782-39-7 (±)-1-(1-phenylethyl)pyrrolidine 
• 100-52-7 benzaldehyde 
• 93-58-3 benzoic acid methyl ester 
• 530-55-2 2,6-dimethoxy-p-quinone 
• 20321-45-3 2-(benzyloxy)-1,3-dimethoxybenzene 
• 582-24-1 1-phenyl-2-hydroxyethanone 

Relevant articles and documents

Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers

A ruthenium-catalyzed, redox neutral C-O bond cleavage of 2-aryloxy-1-arylethanols was developed that yields cleavage products in 62-98% isolated yield. This reaction is applicable to breaking the key ethereal bond found in lignin-related polymers. The bond transformation proceeds by a tandem dehydrogenation/reductive ether cleavage. Initial mechanistic investigations indicate that the ether cleavage is most likely an organometallic C-O activation. A catalytic depolymerization of a lignin-related polymer quantitatively yields the corresponding monomer with no added reagent.

Visible-light-induced C-C bond cleavage of lignin model compounds with cyanobenziodoxolone

The catalytic degradation of lignin to value-added chemicals has received considerable attention over the past decade. Photocatalysis provides promising approaches to enable previously inaccessible transformations. However, examples of the visible-light promoted degradation of lignin are still limited. In this work, the visible-light-induced selective C-C bond cleavage of β-O-4 lignin model compounds has been disclosed via β-scission of in situ generated alkoxy radical intermediates. With cyanobenziodoxolone as the oxidant, a variety of substrates could be transformed into aldehydes in moderate to good yields. In addition, unexpected acetal esters which could conveniently furnish formaldehyde and phenols by alcoholysis were observed.

Au-Pd alloy cooperates with covalent triazine frameworks for the catalytic oxidative cleavage of β-O-4 linkages

To design highly efficient catalysts for the cleavage of the C-O/C-C bond is the key task in the depolymerization of lignin. Bimetallic alloy catalysts Au-Pd-CTFs were developed to be effective in the oxidative cleavage of β-O-4 lignin model compounds with O2. Au-Pd nanoparticles with an Au/Pd molar ratio between 1?:?1 and 1?:?1.5 showed the highest cleavage efficiency. The kinetics of the reaction process revealed that a synergistic effect between Au and Pd played a crucial role in the oxidation of Cα-OH into CαO, which was the rate-determining step for the whole oxidative cleavage process. Further insight revealed that the cooperative effect between Au-Pd nanoparticles and the support covalent triazine frameworks (CTFs) facilitated the cleavage of the formed β-O-4 ketone compound to the corresponding aromatics. In addition, Au-Pd-CTF catalysts also showed efficiency in the oxidative transformation of the organosolv lignin. This catalytic system will provide guidance in the oxidative cleavage of β-O-4 linkages in lignin.