145930-95-6

Basic information

• Product Name: (2-Oxo-2-phenyl-ethyl)-[1-phenyl-1-pyrrolidin-1-yl-meth-(E)-ylidene]-sulfonium; bromide
• Synonyms: (2-Oxo-2-phenyl-ethyl)-[1-phenyl-1-pyrrolidin-1-yl-meth-(E)-ylidene]-sulfonium; bromide
• CAS NO: 145930-95-6
• Molecular Weight: 390.344
• Mol File: 145930-95-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2-Oxo-2-phenyl-ethyl)-[1-phenyl-1-pyrrolidin-1-yl-meth-(E)-ylidene]-sulfonium; bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Oxo-2-phenyl-ethyl)-[1-phenyl-1-pyrrolidin-1-yl-meth-(E)-ylidene]-sulfonium; bromide(145930-95-6)
• EPA Substance Registry System: (2-Oxo-2-phenyl-ethyl)-[1-phenyl-1-pyrrolidin-1-yl-meth-(E)-ylidene]-sulfonium; bromide(145930-95-6)

Safety Data

• Hazardous Substances Data: 145930-95-6(Hazardous Substances Data)

Upstream product

• 15563-45-8 1-thiobenzoylpyrrolidine 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 144651-59-2 3-pyrrolidino-1,3-diphenyl-2-propen-1-one 

Relevant articles and documents

STUDY OF THE ESCHENMOSER SULFIDE CONTRACTION METHOD WITH AND WITHOUT A THIOPHILE

Results obtained and observations made by applying the title method for the synthesis of enaminones 5a-o, using triphenylphosphine as a thiophile and triethylamine as a base, are reported.The product distributions of the deprotonations of α-phenacylthio iminium bromides with and without thiophile and those known from thiouronium and heterocyclic thionium analogs are compared.Key words: Enaminones; α-phenacylthio iminium bromides; disulfides; thiiranes.