146175-56-6

Basic information

• Product Name: Borane, bromodihydroxy-
• CAS NO: 146175-56-6
• Molecular Formula: BBrH2O2
• Molecular Weight: 124.73
• Mol File: 146175-56-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Borane, bromodihydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Borane, bromodihydroxy-(146175-56-6)
• EPA Substance Registry System: Borane, bromodihydroxy-(146175-56-6)

Safety Data

• Hazardous Substances Data: 146175-56-6(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 98-80-6 phenylboronic acid 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 99-90-1 para-bromoacetophenone 

Relevant articles and documents

Synthesis, structure and catalytic application of palladium(II) complexes bearing N-heterocyclic carbenes and phosphines

A variety of mixed palladium(II) complexes bearing N-heterocyclic carbenes (NHCs) and triaryl- and trialkylphosphines [NHC(R2)]Pd(PR′3)I2 (R=Me, t-Bu, (R)-1-phenylethyl; R′=Ph, o-tolyl, cyclohexyl, t-Bu) have been prepared. Crystal structure details of trans-diiodo(1,3-di-tert-butylimidazolin-2-ylidene)(triphenylphosphino) palladium(II) are presented. The complexes were tested as catalysts in the Mizoroki-Heck, Suzuki-Miyaura and Stille reactions as well as in the dimerization of phenylacetylene. In catalytic studies of the Suzuki-Miyaura cross-coupling reaction, the performance of these novel complexes was compared to the results obtained by the corresponding bis(NHC) and bis(phosphine) complexes.