146399-93-1Relevant articles and documents
Large-scale synthesis of D-mannose 6-phosphate and other hexose 6-phosphates
Meldal, Morten,Christensen, Mette Knak,Bock, Klaus
, p. 115 - 128 (1992)
The syntheses of D-mannose 6-phosaphate (4), several D-mannopyranoside 6-phosphates, and methyl α-D-glucopyranoside 6-phosphate are described.Phophorylation of methyl 2,3,4-tri-O-(trimethylsilyl)-α-D-mannopyranoside (2) with phosphorus oxychloride followe
Influence of acyl groups on glucopyranoside reactivity in Lewis acid promoted anomerisation
Farrell, Mark P.,Doyle, Lisa M.,Murphy, Paul V.
supporting information, p. 2726 - 2731 (2018/06/20)
Lewis acid promoted anomerisation has potential in O- or S-glycoside synthesis. Herein, the anomerisation kinetics of thirty-one β-D-glucopyranosides was determined to determine how particular acyl protecting groups and their location influence reactivity towards a Lewis acid promoted reaction. The replacement of acetyl groups with benzoyl groups led to reduced reactivity when located at O-3, O-4 and O-6. However a reactivity increase was observed when the acetyl group was replaced by a benzoyl group at O-2. The 2,3,4,6-tetra-O-(4-methoxy)benzoate had an ~2-fold increase in rate when compared to the tetrabenzoate.
ANTI-ADHESIVE COMPOUNDS TO PREVENT AND TREAT BACTERIAL INFECTIONS
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Page/Page column 11, (2008/06/13)
The present invention provides compounds and compositions capable of inhibiting the attachment of Gram-negative bacteria on a host epithelium. Accordingly, said compounds and compositions can for example be used for the manufacture of a medicament to trea