147166-25-4

Basic information

• Product Name: naphthalen-2-yl(phenyl)selane
• Synonyms: naphthalen-2-yl(phenyl)selane
• CAS NO: 147166-25-4
• Molecular Weight: 283.231
• Mol File: 147166-25-4.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: naphthalen-2-yl(phenyl)selane(CAS DataBase Reference)
• NIST Chemistry Reference: naphthalen-2-yl(phenyl)selane(147166-25-4)
• EPA Substance Registry System: naphthalen-2-yl(phenyl)selane(147166-25-4)

Safety Data

• Hazardous Substances Data: 147166-25-4(Hazardous Substances Data)

Upstream product

• 116569-15-4 naphthalene-2-selenenyl bromide 
• 100-56-1 phenylmercury(II) chloride 
• 87137-17-5 2-selenocyanatonaphthalene 
• 591-51-5 phenyllithium 
• 580-13-2 2-bromonaphthalene 
• 1666-13-3 diphenyl diselenide 
• 2179-79-5 phenyl selenocyanate 
• 32316-92-0 naphthalene-2-boronic acid 
• 645-96-5 Benzeneselenol 
• 591-50-4 iodobenzene 
• 17932-23-9 bis(2-naphthyl) diselenide 
• 93-09-4 naphthalene-2-carboxylate 
• 91-59-8 naphthalen-2-ylamine 
• 71098-88-9 N-phenylselanylphthalimide 

Downstream Products

• 132648-10-3 dichloro-[2]naphthyl-phenyl-λ⁴-selane 

Relevant articles and documents

Palladium Complex Immobilized on Magnetic Nanoparticles Modified with 2-Aminopyridine Ligand: A Novel and Efficient Recoverable Nanocatalyst for C–S and C–Se Coupling Reactions

A novel, versatile and efficient magnetically recoverable palladium nanocatalyst [Fe3O4@SiO2/2-aminopyridine-Pd(II)] was fabricated via the immobilization of palladium(II) complex on the surface of magnetic nanoparticles modified with 2-aminopyridine ligand. The structure of the as-fabricated Fe3O4@SiO2/2-aminopyridine-Pd(II) nanocomposite was characterized by a series of spectroscopic techniques including FT-IR, SEM, TEM, EDX, TGA, XRD, VSM and ICP-OES techniques. The Fe3O4@SiO2/2-aminopyridine-Pd(II) nanocomposite was utilized under mild and eco-friendly conditions in C–S and C–Se coupling reactions to afford a vast variety of diaryl sulfides and diaryl selenides with good to excellent yields. This heterogeneous palladium catalyst can be magnetically separated and reused for at least 7 consecutive trials without any reduction in activity. Graphical Abstract: [Figure not available: see fulltext.]

Forging C?S(Se) Bonds by Nickel-catalyzed Decarbonylation of Carboxylic Acid and Cleavage of Aryl Dichalcogenides

A nickel-catalyzed decarbonylation of carboxylic acids cross-coupling protocol has been developed for the straightforward C?S(Se) bond formation. This reaction is promoted by a commercially-available, user-friendly, inexpensive, air and moisture-stable nickel precatalyst. Various carboxylic acids and a wide range of aryl dichalcogenide substrates were tolerated in this process which afforded products in good to excellent yields. In addition, the present reaction can be conducted on gram scale in good yield.

Metal-Free Synthesis of Unsymmetrical Aryl Selenides and Tellurides via Visible Light-Driven Activation of Arylazo Sulfones

A protocol for the visible light driven preparation of unsymmetrical (hetero)aryl selenides and tellurides is described herein. The method exploits the peculiar photoreactivity of arylazo sulfones that act as thermally stable, precursors of aryl radicals under both photocatalyst- and additive-free conditions. The method developed shows an impressive versatility (more than fifty compounds isolated).